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Arylboronic Acids Coupling Reactions Palladium Organic-Synthesis Ligands Catalysts Efficient Crystal Structure NMR Derivatives Bond Formation Reactivity Water Heck Reaction Aldehydes Room-Temperature Molecular-Structure Hydrosilyation N-Heterocyclic Carbenes Cross-Coupling Reactions Complexes Coordination Chemistry Chemistry Aryl Chlorides Ketones Metal-Complexes Amines Oxidation Copper X-Ray