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Membrane Efficient Synthesis Antimicrobial Peptides Hydrophobicity Derivatives Backbone Amide Linker Solid-Phase Synthesis Receptor Design Proteins Peptide Inhibitor Expression Chemistry Azides Affinity Neuropeptide-Y Ligation Mimicry Fusion Circular Permutation Analogs Peptides Membranes Mechanism Native Chemical Ligation Expressed Protein Ligation Escherichia-Coli Terminal Alkynes CD Spectroscopy Peptide Synthesis