Principles of Physical Chemistry, 2nd Edition
March 2009, ©2009
List of Justifications.
List of Symbols.
1 Wave–Particle Duality.
2 Essential Aspects of Structure and Bonding.
3 Schrödinger Equation.
4 Hydrogen Atom.
5 Atoms and the Variational Principle.
6 A Quantitative View of Chemical Bonding.
7 Bonding Described by Electron Pairs and Molecular Orbitals.
8 Molecules with π-Electron Systems.
9 Absorption of Light.
10 Emission of Light.
11 Nuclei: Particle and Wave Properties.
12 Nuclear Spin.
13 Solids and Intermolecular Forces.
14 Thermal Motion of Molecules.
15 Energy Distribution in Molecular Assemblies.
16 Work w, Heat q, and Internal Energy U.
17 Reversible Work wrev, Reversible Heat qrev, and Entropy S.
18 General Conditions for Spontaneity and its Application to Equilibria of Ideal Gases and Dilute Solutions.
19 Formal Thermodynamics and its Application to Phase Equilibria.
20 Real Gases.
21 Real Solutions.
22 Reaction Equilibria in Aqueous Solutions and Biosystems.
23 Chemical Reactions in Electrochemical Cells.
24 Chemical Kinetics.
25 Transition States and Chemical Reactions.
27 Organized Molecular Assemblies.
28 Supramolecular Machines.
29 Origin of Life: Matter Carrying Information.
HORST-DIETER FÖRSTERLING, Dr. phil., was a Professor in the Department of Physical Chemistry at the Philipps-University of Marburg from 1972 until his retirement in 1999. Professor Försterling has taught physical chemistry courses and laboratory courses at all levels, including graduate and advanced graduate courses in spectroscopy, statistical mechanics, reaction kinetics, and quantum mechanics. His research interests include quantum chemistry, reaction mechanisms, oscillating chemical reactions, and chemical waves.
DAVID H. WALDECK, PhD, is Professor and Chair in the Department of Chemistry at the University of Pittsburgh. Professor Waldeck has taught chemistry courses at all levels, including graduate and advanced graduate courses in statistical mechanics, reaction dynamics, and quantum mechanics. His research interests include condensed-phase reaction dynamics (homogeneous and heterogeneous), solute-solvent interactions (structural and dynamical characteristics), relaxation processes in solids, and electron transport at the nanometer scale.
Chemical equilibria and reactions chapters are enhanced with a more molecular and statistical perspective
Chapter 21 on kinetics has been expanded to underscore the importance of potential energy (or free energy) curves in view of reaction kinetics and to make important connections to modern studies in electron transfer reactions, 'femtochemistry', and reaction dynamics
Discussion of solids and nanoscale materials (quantum dots, nanotubes, etc).
the 'Problems' (worked examples) have been integrated into each chapter, rather than presented at the end of the chapter
A set of problems to be worked by the student will be presented at the end of each chapter (solutions will be provided in a separate format)
Provides students with computer exercises, using MathCAD modules in which the student can change the parameters and observe how the system changes
- Provides a simple model to understand the essence of quantum mechanics and why atoms and molecules exist (electron-in-a-box model)
- Exposes beginners to statistical thermodynamics
- Includes largely neglected topics in the present day curriculum, such as: macromolecules, the principles of organized molecular assemblies, the construction of supramolecular machines and the basic mechanism in the emergence of information producing and carrying forms of matter
- Provides a CD-ROM with interactive MATHCAD exercises and data tables with search functions
- A solution's manual is available
Recommended. Upper-division undergraduate through professional collections". (Choice, 1 November 2010)
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