 
Six-Membered Transition States in Organic Synthesis
ISBN: 978-0-470-19904-6
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200 pages
February 2008
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Introduction.
1 [3,3]-Sigmatropic Rearrangements.
General Considerations.
Reactions.
1.1 Claisen Rearrangement.
1.2 Johnson–Claisen Rearrangement.
1.3 Ireland–Claisen Rearrangement.
1.4 Cope Rearrangement.
1.5 Anionic Oxy-Cope Rearrangement.
1.6 Aza-Cope–Mannich Reaction.
2 Aldol Reactions.
General Considerations.
Reactions.
2.1 Asymmetric Syn-Aldol Reaction.
2.2 Asymmetric Anti-Aldol Reaction.
2.3 Proline-Catalyzed Asymmetric Aldol Reaction.
3 Metal Allylation Reactions.
General Considerations.
Reactions.
3.1 Boron Allylation Reaction.
3.2 Silicon Allylation Reaction.
4 Stereoselective Reductions.
General Considerations.
Reactions.
4.1 Diastereoselective Syn-Reduction of β-Hydroxy Ketones.
4.2 Diastereoselective Anti-Reduction of β-Hydroxy Ketones.
4.3 Asymmetric Reduction.
List of Copyrighted Materials.
Abbreviations.
Subject Index.
Scheme Index of Natural Products.
