Wiley
Wiley.com
Print this page Share

Cumulenes in Click Reactions

ISBN: 978-0-470-77932-3
562 pages
December 2009
Cumulenes in Click Reactions (0470779322) cover image
Cumulenes are organic molecules with two or more cumulative (consecutive) double bonds. Their reactions often proceed at room temperature, with or without a catalyst, and are stereospecific, giving the reaction products in high yields – features characteristic of “click reactions”. 

Cumulenes in Click Reactions presents a comprehensive list of cumulene systems and their reactions, with an emphasis on their “click-like” nature. The chapters are structured according to the number of carbon atoms in the system, including coverage of:

  • introduction to the chemistry of cumulenes
  • one-carbon cumulenes: sulfines, sulfenes, thiocarbonyl S-imides, thiocarbonyl S-sulfides, and 1-aza-2-azoniaallene salts
  • two-carbon cumulenes: carbon oxides, carbon sulfides, carbon nitrides (isocyanates, isothiocyanates, and carbodiimides), phosphaallenes, and diarsaallenes
  • 1,2-dicarbon cumulenes: ketenes, thioketenes, ketenimines, 1-silaallenes, 1-phosphaallenes, and other metal allenes
  • 1,3-dicarbon cumulenes: thiocarbonyl S-ylides, 2-azaallenium salts, 1-oxa-3-azoniabutatriene salts, 1-thia-3-azoniabutatriene salts, and phosphorous ylides
  • 1,2,3-tricarbon cumulenes: allenes, butatrienes, higher cumulenes and heterobutatrienes
  • noncarbon cumulenes: azides, triazaallenium salts, sulfur oxides, sulfur nitrides, N-sulfinylamines, sulfurdiimides, and dithionitronium cation

Cumulenes in Click Reactionsis an essential guide for researchers and advanced students in academia and research working in synthetic organic, inorganic and bioorganic chemistry.

See More
Preface

Acknowledgements

1 General Introduction

References

2 1-Carbon Cumulenes

2.1 Sulfines, R2C SO

2.2 Sulfenes, R2C S(O)O

2.3 Other 1-Carbon Cumulenes

3 2-Carbon Cumulenes

3.1 Carbon Oxides, O C O, :CO

3.2 Carbon Sulfides, S C S, S CO

3.3 Carbon Nitrides

3.4 Center Carbon Phosphorallenes, P C P

4 1,2-Dicarbon Cumulenes

4.1 Ketenes, R2C C O

4.2 Thioketenes, R2C C S

4.3 Ketenimines, R2C C NR

4.4 1-Silaallenes, R2C C Si

4.5 1-Phosphaallenes, R2C C P

4.6 Other Metal Allenes

5 1,3-Dicarbon Cumulenes

5.1 Thiocarbonyl S-ylides, R2C S CH2

5.2 2-Azaallenium Salts, R(Ce)C N+ C(Ce)R

5.3 1-Oxa-3-azoniabutatriene Salts, R2C N+ C O

5.4 1-Thia-3-azabutatriene Salts, R2C N+ C S

5.5 Phosphorus Ylides

6 1,2,3-Tricarbon Cumulenes

6.1 Allenes, R2C CR2

6.2 [3] Cumulenes, R2C C C CR2

6.3 [4] Cumulenes, R2C C C C CR2

6.4 [5] Cumulenes, R2C C C C C CR2

7 Noncarbon Cumulenes

7.1 Azides, RN N N

7.2 Triazaallenium Salts, RN N+ NR

7.3 Sulfur Oxides

7.4 Sulfur Nitrides

7.5 Cationic Boron Cumulenes, R2N B NR

Index

See More
January 25, 2010
Cumulenes in Click Reactions

Wiley is pleased to announce the publication of the first ever book on the chemistry of cumulenes. Cumulenes in Click Reactions expands the scope of the hot topic:  click chemistry.

Cumulenes are organic molecules with two or more cumulative (consecutive) double bonds. Their reactions often proceed at room temperature, with or without a catalyst, and are stereospecific, giving the reaction products in high yields - these are all characteristic features of click reactions. Click reactions are a current hot topic in organic synthesis.

Written by a well-known authority in the field, Henri Ulrich, Cumulenes in Click Reactions presents a comprehensive list of cumulene systems and their reactions, with an emphasis on their "click-like" nature. The chapters are structured according to the number of carbon atoms in the system.

Cumulenes in Click Reactions will be an invaluable resource for researchers and advanced students in industry and academia working in the fields of synthetic organic, inorganic and bioorganic chemistry.


Contents

Introduction

One-Carbon Cumulenes: sulfines, sulfenes, thiocarbonyl S-imides, thiocarbonyl S-sulfides, and 1-aza-2-azoniaallene salts.

Two-Carbon Cumulenes: carbon oxides, carbon sulfides, carbon nitrides (isocyanates, isothiocyanates, and carbodiimides), phosphaallenes, and diarsaallenes.

1,2-Dicarbon Cumulenes: ketenes, thioketenes, ketenimines, 1-silaallenes, 1-phosphaallenes, and other metal allenes.

1,3-Dicarbon Cumulenes: thiocarbonyl S-ylides, 2-azaallenium salts, 1-oxa-3-azoniabutatriene salts, 1-thia-3-azoniabutatriene salts, and phosphorous ylides.

1,2,3-Tricarbon Cumulenes: allenes, butatrienes, higher cumulenes and heterobutatrienes.

Noncarbon Cumulenes: azides, triazaallenium salts, sulfur oxides, sulfur nitrides, N-sulfinylamines, sulfurdiimides, and dithionitronium cation.

See More
Buy Both and Save 25%!
+

Cumulenes in Click Reactions (US $240.00)

-and- Organic Synthesis Using Transition Metals, 2nd Edition (US $65.00)

Total List Price: US $305.00
Discounted Price: US $228.75 (Save: US $76.25)

Buy Both
Cannot be combined with any other offers. Learn more.
Back to Top