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The Chemistry of Anilines, Part 1

Zvi Rappoport (Editor)
ISBN: 978-0-470-87171-3
1180 pages
April 2007
The Chemistry of Anilines, Part 1 (0470871717) cover image


Aniline is the parent molecule of a vast family of aromatic amines. Since its discovery in 1826 it has become one of the hundred most important building blocks in chemistry. Aniline is used as an intermediate in many different fields of applications, such as isocyanates, rubber processing chemicals, dyes and pigments, agricultural chemicals and pharmaceuticals.

The understanding of functional groups is key for the understanding of all organic chemistry. In the tradition of the Patai Series, this volume treats all aspects of this functional group. It contains chapters on the theoretical and computational foundations; on analytical and spectroscopical aspects with dedicated chapters on Mass Spectrometry, NMR, IR/UV, etc.; on reaction mechanisms; on applications in syntheses.

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Table of Contents

1 Anilines: Historical background (Anthony S. Travis).

2 General and theoretical aspects of anilines (Minh Tho Nguyen).

3 Structural chemistry of anilines (Grazyna Maria Wojcik).

4 Thermochemistry of anilines (Suzanne W. Slayden and Joel F. Liebman).

5 Mass spectrometry and gas-phase chemistry of anilines (Marcos N. Eberlin, Daniella Vasconcellos Augusti and Rodinei Augusti).

6 NMR spectra of anilines (Erkki Kolehmainen, Ryszard Gawinecki and Borys Osmiałowski).

7 Substituted anilines as solvatochromic probes (Yizhak Marcus).

8 Hydrogen bonds of anilines (Luciano Forlani).

9 Synthesis of anilines (John F. Hartwig, Shashank Shekhar, Qilong Shen and Fabiola Barrios-Landeros).

10 Anilines as nucleophiles (Ikchoon Lee and Dae Dong Sung).

11 Rearrangements of anilines and their derivatives (Sergei M. Lukyanov and Alla V. Koblik).

12 Analytical aspects of aromatic amines (Jacob Zabicky).

13 Manufacture and uses of the anilines: A vast array of processes and products (Anthony S. Travis).

14 The spectroscopy, photophysics and photochemistry of anilines (Jye-Shane Yang).

15 Toxicological and environmental aspects of anilines (Anthony S. Travis).

16 Electrochemistry of anilines (Jan S. Jaworski and Marek K. Kalinowski).

17 Proton sponges (Alexander F. Pozharskii and Valery A. Ozeryanskii).

Author index.

Subject index.

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"Like others in the series, this is a hefty, comprehensive set of up-to-date volumes on a specialized topic…" (Journal of the American Chemical Society, August 8, 2007)
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