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Inorganic and Organometallic Reaction Mechanisms, 2nd Edition

ISBN: 978-0-471-18897-1
328 pages
February 1997
Inorganic and Organometallic Reaction Mechanisms, 2nd Edition (0471188972) cover image
This title provides detailed coverage of classic inorganic reaction mechanisms and organometallic reaction mechanisms. The coverage of the mechanisms expected for reactions of transitions metal complex includes the kinetic studies used to differentiate possible mechanisms. This combination of coordination complexes and organometallic complexes is unique to this title. Describing how transition metal complexes react and the type of data used to determine how complexes react, this work provides excellent introductions, extensive problems, and thought-provoking summaries in every chapter. Complete with excellent references, this second edition has been updated with new problems and increased information on NMR techniques, dissociative reactions of square-planar complexes, seventeen-electron complexes, organometallic transfer, and oxidative-addition and reductive-elimination reactions. The only current text on inorganic mechanisms, this book is ideal for students and chemists who deal with inorganic and organometallic reagents.
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Rate Laws/
Activation Parameters/
Microscopic Reversibility/
Linear Free Energy Relationships/
Kinetic Techniques/
Classification of Mechanisms/
Substitution Reactions/
Trans Effect/
Other Effects/
Activation Parameters/
Dissociative Processes/
Other Metal Centers/
Kinetics/
Mechanisms/
Leaving Group, Chelate and Ligand Effects/
Effect of Metal/
Stereochemistry/
Ligand Bonding/
Metal Carbonyl Substitution Reactions/
Dissociation of Other Ligands/
Ligand Effects/
Complexes with Seventeen Electrons/
Substitution on Metal Carbonyl Complexes Containing Metal-Metal Bonds/
Ligand Substitution Reactions on Alkyl Complexes/
Hydride Complexes/
Nitrosyl, Allyl and Other Complexes/
Oxidative Addition/
Reductive Elimination /Homogeneous Hydrogenation of Alkenes/
Asymmetric Hydrogenation/
Hydroformylation/
Wacker Acetaldehyde Synthesis/
Hydrocyanation of 1,3-Butadiene/
Olefin Metathesis/
Polymerization of Alkenes/
Methanol Carboylation/
Coordination Number Isomerization/
Metal Migration in an Unsaturated Ring -
Ring Whizzers/
Metal-Metal Bonded Systems/
Outer Sphere Electron Transfer/
Long-Range Electron Transfer/
Multielectron Transfer/
Organometallic Electron Transfer.
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