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Inorganic Syntheses, Volume 26

Herbert D. Kaesz (Editor-in-Chief)
ISBN: 978-0-471-50485-6
443 pages
November 1989
Inorganic Syntheses, Volume 26 (0471504858) cover image
The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.
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Chapter One COMPOUNDS OF THE MAIN GROUP ELEMENTS AND THE LANTHANIDES.

1. Potassium Tetradecahydrononaborate(1-).

2. Bromotrimethylsilane.

3. Trimeth ylphosphine.

4. Phosphorus Trifluoride.

5. (η5-Cyclopentadienyl)lanthanide Complexes from the Metallic Elements.

Chapter Two MONONUCLEAR TRANSITION METAL COMPLEXES Part I.

6. Ammonium [( 1R)-(endo, anti)]-3-bromo-l, 7-dimethyl-2-oxobicyclo [2.2.1] heptane-7-met hanesulfonate, and Synthesis and Resolution of cis-Dichlorobis (1,2-ethanediamine)-chromium(III) Chloride.

7. Organometallic Complexes of Isomeric Acyl Isocyanides Chromium Carbonyl (Acyl Isocyanide) and (Acyl Cyanide) Complexes.

8. Diammonium pentachlorooxomolybdate(V).

9. Carbyne Complexes of Tungsten.

10. (2, 2-Dimethylpropylidyne)tungsten(VI) Complexes and Precursors for Their Syntheses.

11. Zerovalent Iron Isocyanide Complexes.

12. Tetracarbonyliron(0) Complexes Containing Group V Donor Ligands.

13. cis-Tetraamminedihaloruthenium(III) Halide Complexes.

14. (η4-1, 5-Cyclooctadiene)ruthenium(II) Complexes.

15. Pentacarbonylhydridorhenium.

16. Organometallic Fluoro Complexes.

17. (Tetrahydrothiophene)gold(I) or Gold(III) Complexes.

Chapter Three MONONUCLEAR TRANSITION METAL COMPLEXES Part 11. COMPLEXES WITH WEAKLY BONDED ANIONS.

Preface (W. Beck).

18. Carbonyl(η5-cyclopentadienyl) (tetrafluoroborato) molybdenum and -tungsten Complexes.

19. Pentacarbonyl(tetrafluoroborato) rhenium and -manganese and Reactions Thereof.

20. Manganese(I) and Rhenium(I) Pentacarbonyl (trifluoromethanesulfonato) Complexes.

21. Iridium(III) Complexes with the Weakly Bonded Anions [BF4]-, and [OSO2CF3]-.

22. Dihydridobis(solvent) bis(triphenylphosphine)iridium(III) Tetrafluoroborates.

23. cis-Chlorobis(triethy1phosphine)- (trifluoromethanesulfonato)platinum(II).

24. Acetonitrile Complexes of Selected Transition Metal Cations.

25. The Formation of the Hydrido(methanol) bis(triethylphosphine) platinum(II) Cation and Its Reactions with Unsaturated Hydrocarbons.

Chapter Four MONONUCLEAR TRANSITION METAL COMPLEXES Part III. METALLOCYCLIC COMPLEXES.

Preface (E. Lindner).

26. Main Group Metal (Li or Mg) o-Phenylenedimethyl [o-C6H4(CH2)2 or o-C6H4{CH(SiMe3)}2] Transfer Reagents.

27. Cyclometallated Organolithium Compounds.

28. Metallation of Aromatic Ketones with Pentacarbonylmethylmanganese(I).

29. Cyclo-Cotrimorization of Phosphinothioyls with Alkynes. Phosphinothioyl-containing Manganese Analogs of Cyclopentadiene and Bicycloheptadienes.

30. Tetracarbonyli {[2-(diphenylphosphino) phenyl] hydroxymethyl-C, P}manganese.

31. Cyclometallation Reactions.

32. (η6-Hexamethy1benzene) ruthenium Complexes Containing Hydride and ortho-Metallated Triphenylphosphine.

33. An Osmium Containing Benzene Analog, Os(CSCHCHCHCH) (CO) (PPh3)2, Carbonyl (5-thioxo-1, 3-pentadiene-l, 5-diyl-C1, C5, S) bis(triphenylphosphine) osmium and Its Precursors.

34. (1, 3-butadiene-1, 4-diyl) (η5-Cyclopentadienyl)- (triphenylphosphine)cobalt with Various Substituents.

35. An Iridium(III) Complex Containing Cyclometallated Triphenylphosphine Formed by Isomerization of an Iridium(I) Triphenylphosphine Complex.

36. Nickel-Containing Cyclic Amide Complexes.

37. Six-Membered Cyclopalladated Complexes of 2-Benzylpyridine.

38. Cyclopalladated Compounds.

Chapter Five POLYNUCLEAR TRANSITION METAL COMPLEXES.

Preface (J. R. Shapley).

39. Ditungsten Tetracarboxylates.

40. Diphenylphosphino-Bridged Dimanganese Complexes.

41. Preparation of Some Bimetallic μ-(η1-C,O) Acetyl Complexes

42. Trinuclear Metal Complexes.

43. Bis[μ-nitrido-bis(triphenylphosphorus) (1+)[μ4- carbido-dodecacarbonyltetraferrate(2-)].

44. Dinuclear Ruthenium(II) Carboxylate Complexes.

45. Polynuclear Ruthenium Complexes.

46. A Phosphino Bridged Ruthenium Cluster: Nonacarbonyl- μ-hydrido- (μ-diphenylphosphino)triruthenium(0).

47. [μ-Nitrido-bis (triphenylphosphorus) (1+)] [decacarbonyl - 1k3C, 2k3C, 3k4C-μ-hydrido-l:2k2 H-bis- (triethylsily1)-1KSi, 1KSi) triangulo-trimthenate(1-)].

48. Tri- and Tetranuclear Carbonyl-Ruthenium Cluster Complexes Containing Isocyanide, Tertiary Phosphine, and Phosphite Ligands. Radical Ion-Initiated Substitution of Metal Cluster Carbonyl Complexes Under Mild Conditions.

49. Carbido-carbonyl Ruthenium Cluster Complexes.

50. Nitrido-Ruthenium Cluster Complexes.

51. Some Useful Derivatives of Dodecacarbonyltriosmium.

52. Dodecacarbonyltetra -μ-hydrido -tetrahedro-tetraosmium.

53. High Nuclearity Carbonyl Cluster Complexes of Osmium.

54. Thioosmium Clusters.

55. Tris(η5-cyclopentadienyl) bis(μ3- phenylmethy1idyne)- tricobalt.

56. Bis(tetramethy1ammonium) Hexa-μ-carbonyl- hexacarbonylhexanickelate (2-), [N(CH3)4]2 [Ni6(CO)6(μ-CO)6].

57. Bis(tetrabuty1ammonium) Hexa-μ-carbonyl- hexacarbonylhexaplatinate (2-), [N(C4H9)4]2 [Pt6(CO)6(μ-CO)6].

58. Preparation of the Carbonyl Platinum Anions, [Pt3(CO)6]2-n (n = 3-5).

59. Synthesis of Gold-Containing Mixed-Metal Cluster Complexes.

60. Mercury-Bridged Transition Metal Cluster Derivatives and Their Precursor.

61. Heterobinuclear Nonacarbonyl Complexes and Hydride Complexes of Iron-Chromium, Iron-Molybdenum, and Iron - Tungsten.

62. Cyclopentadienylsodium and some Mono-, Tri-, and Tetranuclear Metal Carbonyl Derivatives and Cluster Complexes.

63. Mixed Trinuclear Dicobaltiron and Dicobaltruthenium Cluster Complexes.

64. Stepwise Syntheses of Ruthenium Mixed-Metal Cluster Complexes.

65. Mixed-Metal Cluster Complexes of Nickel with Ruthenium or with Osmium.

66. Triosmium and Trinickeltriosmiurn Cluster Complexes.

67. A. Dicobaltplatinum Complex and Its Platinum Precursor.

68. Salts of Mixed Platinum-Tetrarhodium Cluster Complexes.

Chapter Six SOLID STATE.

69. Synthesis and Crystal Growth of A3[M2X9](A = Cs, Rb; M = Ti, V, Cr; X = C1, Br).

70. Highly Conducting and Superconducting Synthetic Metals.

Index of Contributors.

Subject Index.

Formula Index.

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