WILEY

KNOWLEDGE FOR GENERATIONS

WILEY - KNOWLEDGE FOR GENERATIONS

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Handbook of Metathesis, Three Volume Set
ISBN: 978-3-527-30616-9
Hardcover
1234 pages
November 2003
US $755.00 Add to Cart

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  • Description
  • Table of Contents
  • Reviews
Preface.

CATALYST DEVELOPMENTS.

Introduction.

The Role of the "Tebbe Complex" in Olefin Metathesis.

The Discovery and Development of High Oxidation State Mo and W Imido Alkylidene Complexes for Alkene Metathesis.

From ill-defined to well-defined W alkylidene complexes.

Discovery of Well-defined Ruthenium Olefin Metathesis Catalysts.

Synthesis of Ruthenium Carbene Complexes.

ynthesis of Rhodium and Ruthenium Carbene Complexes with a 16-Electron Count.

Mechanism of Ruthenium-Catalyzed Olefin Metathesis Reactions.

Intrinsic Reactivity of Ruthenium Carbenes.

The Discovery and Development of High Oxidation State Alkylidyne Complexes for Alkyne Metathesis

.Well-defined Metallocarbenes and Metallocarbynes Supported on Oxide Support prepared via Surface Organometallic Chemistry

.APPLICATIONS IN ORGANIC SYNTHESIS.

Introduction.

General Ring-Closing Metathesis.

Catalytic Asymmetric Olefin Metathesis.

Tandem RCM.

Ene-Yne Metathesis.

Ring Opening Cross Metathesis.

Ring Expansion Metathesis Reactions.

Olefin Cross-Metathesis.

The Olefin Metathesis Reaction in Complex Molecule Construction.

Applications of Ring Closing Metathesis to Alkaloid Synthesis.

Radicicol and the Epothilones: Total Synthesis of Novel Anti Cancer Agents Using Ring Closing Metathesis.

The Use of Olefin Metathesis in Combinatorial Chemistry: Supported and Chromatography-Free Syntheses.

Metal-Catalyzed Olefin Metathesis in Metal Coordination Spheres.

Alkyne Metathesis.

Metathesis of silicon-containing olefins.

Commercial Applications of Ruthenium Metathesis Processes.

POLYMER SYNTHESIS.

Introduction.

Living Ring-Opening Olefin Metathesis Polymerization.

Synthesis of Copolymers.

Conjugated polymers.

Stereochemistry of ROMP.

Syntheses and Applications of Bioactive Polymers Generated by the Ring-Opening Metathesis Polymerization (ROMP).

Metathesis Polymerization: A Versatile Tool for the Synthesis of Surface-Functionalized Supports and Monolithic Materials.

Telechelic Polymers from Olefin Metathesis Methodologies.

ADMET Polymerization.

Acyclic Diyne Metathesis Utilizing in Situ Transition Metal Catalysts: An Efficient Access to Alkyne-Bridged Polymers.

Polymerization of Substituted Acetylenes.

Commercial Applications.