Kinetics of Chemical ReactionsISBN: 9783527317639
446 pages
August 2011

This systematic presentation covers both experimental and theoretical kinetic methods, as well as fundamental and applied. The identification of dominant reaction paths, reaction intermediates and ratedetermining steps allows a quantification of the effects of reaction conditions and catalyst properties, providing guidelines for catalyst optimization. In addition, the form in which the equations are presented allows for their straightforward implementation for scaleup and chemical reactor design purposes. Throughout, the methodologies given are illustrated by many examples.
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INTRODUCTION
Overview
Decoding Complexity in Chemical Kinetics
Three Types of Chemical Kinetics
Challenges and Goals. How to Kill Chemical Complexity
What our Book is Not About. Our Book among Other Books on Chemical Kinetics
The Logic in the Reasoning of This Book
How Chemical Kinetics and Mathematics are Interwoven in This Book
History of Chemical Kinetics
CHEMICAL REACTIONS AND COMPLEXITY
Introduction
Elementary Reactions and the MassAction Law
The Reaction Rate and Net Rate of Production of a Component 
A Big Difference
Dimensions of the Kinetic Parameters and Their Order of Magnitude
Conclusions
KINETIC EXPERIMENTS: CONCEPTS AND REALIZATIONS
Introduction
Experimental Requirements
Material Balances
Classification of Reactors for Kinetic Experiments
Formal Analysis of Typical Ideal Reactors
KineticModelFree Analysis
Diagnostics of Kinetic Experiments in Heterogeneous Catalysis
CHEMICAL BOOKKEEPING: LINEAR ALGEBRA IN CHEMICAL KINETICS
Basic Elements of Linear Algebra
Linear Algebra and Complexity of Chemical Reactions
Conclusions
STEADYSTATE CHEMICAL KINETICS: A PRIMER
Introduction to Graph Theory
Representation of Complex Mechanisms as Graphs
How to Derive the Reaction Rate for a Complex Reaction
Derivation of SteadyState Kinetic Equations for a SingleRoute Mechanism 
Examples
Derivation of SteadyState Kinetic Equations for MultiRoute Mechanisms: Kinetic Coupling
STEADYSTATE CHEMICAL KINETICS: MACHINERY
Analysis of Rate Equations
Apparent Kinetic Parameters: Reaction Order and Activation Energy
How to Reveal Mechanisms Based on SteadyState Kinetic Data
Conclusions
LINEAR AND NONLINEAR RELAXATION. STABILITY
Introduction
Relaxation in a Closed System
Stability 
General Concept
Simplifications of NonSteadyState Models
NONLINEAR MECHANISMS: STEADY STATE AND DYNAMICS
Critical Phenomena
Isothermal Critical Effects in Heterogeneous Catalysis: Experimental Facts
Ideal Simple Models: Steady State
Ideal Simple Models: Dynamics
Structure of the Detailed Mechanism and Critical Phenomena: Relationships
NonIdeal Factors
Conclusions
KINETIC POLYNOMIALS
"Linear" Introduction to the Nonlinear Problem: Reminder
"Nonlinear" Introduction
Principles of the Approach: QuasiSteadyState Approximation. Mathematical Basis
Kinetic Polynomials: Derivation and Properties
Kinetic Polynomials: Classical Approximations and Simplifications
Application of Results of the KineticPolynomial Theory: Cycles Across an Equilibrium
Critical Simplification
Concluding Remarks
TEMPORAL ANALYSIS OF PRODUCTS: PRINCIPLES, APPLICATIONS AND THEORY
Introduction
The TAP Experiment
Description and Operation of a TAP Reactor System
Basic Principle of TAP
Position of TAP Among Other Kinetic Methods
Qualitative TAP Data Analysis. Examples
Quantitative TAP Data Description. Theoretical Analysis
Kinetic Monitoring: Strategy of Interrogative Kinetics
Theoretical Frontiers
Conclusions: What Next?
DECODING THE PAST
Chemical Time and Intermediates. Early History
Discovery of Catalysis and Chemical Kinetics
Guldberg and Waage's Breakthrough
Van 't Hoff's Revolution: Achievements and Contradictions
PostVan 't Hoff Period: Reaction Is Not a SingleAct Drama
AllinAll Confusion: Attempts at Understanding
Out of Confusion: Physicochemical Understanding
Towards Mathematical Chemical Kinetics
DECODING THE FUTURE
A Great Achievement, A Great Illusion
A New Paradigm for Decoding Chemical Complexity
Overview
Decoding Complexity in Chemical Kinetics
Three Types of Chemical Kinetics
Challenges and Goals. How to Kill Chemical Complexity
What our Book is Not About. Our Book among Other Books on Chemical Kinetics
The Logic in the Reasoning of This Book
How Chemical Kinetics and Mathematics are Interwoven in This Book
History of Chemical Kinetics
CHEMICAL REACTIONS AND COMPLEXITY
Introduction
Elementary Reactions and the MassAction Law
The Reaction Rate and Net Rate of Production of a Component 
A Big Difference
Dimensions of the Kinetic Parameters and Their Order of Magnitude
Conclusions
KINETIC EXPERIMENTS: CONCEPTS AND REALIZATIONS
Introduction
Experimental Requirements
Material Balances
Classification of Reactors for Kinetic Experiments
Formal Analysis of Typical Ideal Reactors
KineticModelFree Analysis
Diagnostics of Kinetic Experiments in Heterogeneous Catalysis
CHEMICAL BOOKKEEPING: LINEAR ALGEBRA IN CHEMICAL KINETICS
Basic Elements of Linear Algebra
Linear Algebra and Complexity of Chemical Reactions
Conclusions
STEADYSTATE CHEMICAL KINETICS: A PRIMER
Introduction to Graph Theory
Representation of Complex Mechanisms as Graphs
How to Derive the Reaction Rate for a Complex Reaction
Derivation of SteadyState Kinetic Equations for a SingleRoute Mechanism 
Examples
Derivation of SteadyState Kinetic Equations for MultiRoute Mechanisms: Kinetic Coupling
STEADYSTATE CHEMICAL KINETICS: MACHINERY
Analysis of Rate Equations
Apparent Kinetic Parameters: Reaction Order and Activation Energy
How to Reveal Mechanisms Based on SteadyState Kinetic Data
Conclusions
LINEAR AND NONLINEAR RELAXATION. STABILITY
Introduction
Relaxation in a Closed System
Stability 
General Concept
Simplifications of NonSteadyState Models
NONLINEAR MECHANISMS: STEADY STATE AND DYNAMICS
Critical Phenomena
Isothermal Critical Effects in Heterogeneous Catalysis: Experimental Facts
Ideal Simple Models: Steady State
Ideal Simple Models: Dynamics
Structure of the Detailed Mechanism and Critical Phenomena: Relationships
NonIdeal Factors
Conclusions
KINETIC POLYNOMIALS
"Linear" Introduction to the Nonlinear Problem: Reminder
"Nonlinear" Introduction
Principles of the Approach: QuasiSteadyState Approximation. Mathematical Basis
Kinetic Polynomials: Derivation and Properties
Kinetic Polynomials: Classical Approximations and Simplifications
Application of Results of the KineticPolynomial Theory: Cycles Across an Equilibrium
Critical Simplification
Concluding Remarks
TEMPORAL ANALYSIS OF PRODUCTS: PRINCIPLES, APPLICATIONS AND THEORY
Introduction
The TAP Experiment
Description and Operation of a TAP Reactor System
Basic Principle of TAP
Position of TAP Among Other Kinetic Methods
Qualitative TAP Data Analysis. Examples
Quantitative TAP Data Description. Theoretical Analysis
Kinetic Monitoring: Strategy of Interrogative Kinetics
Theoretical Frontiers
Conclusions: What Next?
DECODING THE PAST
Chemical Time and Intermediates. Early History
Discovery of Catalysis and Chemical Kinetics
Guldberg and Waage's Breakthrough
Van 't Hoff's Revolution: Achievements and Contradictions
PostVan 't Hoff Period: Reaction Is Not a SingleAct Drama
AllinAll Confusion: Attempts at Understanding
Out of Confusion: Physicochemical Understanding
Towards Mathematical Chemical Kinetics
DECODING THE FUTURE
A Great Achievement, A Great Illusion
A New Paradigm for Decoding Chemical Complexity
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Professor Guy B. Marin is chair of the Department of Chemical Engineering at Ghent University (Belgium). He received his PhD degree from Ghent University in 1980. He took a position of full professor in 1988 at Eindhoven University of Technology (The Netherlands) where he taught chemical reactors. In 1997 he returned to Ghent as director of the Laboratory for Chemical Technology. He coauthored more tan 300 papers in international journals. Professor Marin is editorinchief of 'Advances in Chemical Engineering' and coeditor of the Chemical Engineering Journal. Chemical reaction and reactor engineering in general and reaction kinetics in particular are the main leads in his research program.
Professor Gregory S. Yablonsky obtained his academic degrees from the Boreskov Institute of Catalysis (Novosibirsk, Russia). From 1995 until 2007, he worked in the Department of Chemical Engineering at Washington University in St. Louis, USA. Since 2007, he is working at Parks College and in the Department of Chemistry at Saint Louis University. Professor Yablonsky has been a Visiting Professor at several universities, in particular the National University of Singapore and Queen's University of Belfast (N. Ireland, UK). Since 2009, Yablonsky is a Honorary Professor of Ghent University. He has served as organizer and chairman of many international conferences on chemical kinetics, catalysis, and mathematical methods in chemical engineering. He has been involved in theoretical kinetics and heterogeneous catalysis research for over 30 years, and is author of more than 200 papers and six books.
Professor Gregory S. Yablonsky obtained his academic degrees from the Boreskov Institute of Catalysis (Novosibirsk, Russia). From 1995 until 2007, he worked in the Department of Chemical Engineering at Washington University in St. Louis, USA. Since 2007, he is working at Parks College and in the Department of Chemistry at Saint Louis University. Professor Yablonsky has been a Visiting Professor at several universities, in particular the National University of Singapore and Queen's University of Belfast (N. Ireland, UK). Since 2009, Yablonsky is a Honorary Professor of Ghent University. He has served as organizer and chairman of many international conferences on chemical kinetics, catalysis, and mathematical methods in chemical engineering. He has been involved in theoretical kinetics and heterogeneous catalysis research for over 30 years, and is author of more than 200 papers and six books.
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“Finally, this book fulfills its aim to be a systematic presentation of the addressed matter for the broad variety of chemistry lecturers and students, graduate students, physical chemists, chemical engineering students and lecturers, physics students and chemical engineers.” (Materials and Corrosion, 1 November 2012)
"It will be most useful to those chemists who have an interest in chemical engineering and/or the kinetics and mechanisms of catalysis within chemical reactors." (Chemistry World, 2012)See More