 Modern Supramolecular Chemistry: Strategies for Macrocycle Synthesis
ISBN: 978-3-527-31826-1
Hardcover
418 pages
April 2008
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List of Contributors.
1 Bioactive Macrocyclic Peptides and Peptide Mimics (Rob M.J. Liskamp, Dirk T.S. Rijkers, and Saskia E. Bakker).
1.1 Introduction.
1.2 Selected Cyclic Peptides.
1.3 Conclusions.
1.4 Experimental: Selected Procedures.
2 Macrocycles by Ring-closure Metathesis (Joëlle Prunet, Anderson Rouge dos Santos, and Jean-Pierre Férézou).
2.1 Introduction.
2.2 How to Cyclize?
2.3 Factors Influencing the Double-Bond Configuration.
2.4 Ene-yne M-RCM.
2.5 Tandem Processes Involving M-RCM.
2.6 Representative Synthetic Applications.
2.7 Conclusion and Perspectives.
2.8 Experimental: Selected Procedures.
3 Supramolecular Macrocycle Synthesis by H-bonding Assembly (Pablo Ballester and Javier de Mendoza).
3.1 Introduction.
3.2 Strategies to Build up Supramolecular Macrocycles Based on Hydrogen Bonds.
3.3 Strategies to Build up Supramolecular Cavities and Capsules Based on Hydrogen Bonds.
3.4 Summary and Outlook.
3.5 Experimental: Selected Procedures.
4 Cucurbit[n]urils (Wei-Hao Huang, Simin Liu, and Lyle Isaacs).
4.1 Introduction.
4.2 New Members of the Cucurbit[n]uril Family.
4.3 Applications of Members of the Cucurbit[n]uril Family.
4.4 Experimental Support for the Proposed Mechanism of CB[n] Formation.
4.5 Direct Functionalization of Cucurbit[n]urils.
4.6 Nor-Seco-Cucurbit[10]uril.
4.7 Summary and Conclusions.
4.8 Experimental: Selected Procedures.
5 Tetra-urea Calix[4]arenes – From Dimeric Capsules to Novel Catenanes and Rotaxanes (Ganna Podoprygorina and Volker Böhmer).
5.1 Introduction.
5.2 Basics of Tetra-urea Calix[4]arenes.
5.3 Preorganization in Dimers of Tetra-urea Calix[4]arenes.
5.4 Multimacrocycles.
5.5 Multiple Catenanes Based on Calix[4]arenes.
5.6 Multiple Rotaxanes.
5.7 Self-sorting and Formation of Larger Assemblies.
5.8 Conclusions and Outlook.
5.9 Experimental: Selected Procedures.
6 Shape-Persistent Macrocycles Based on Acetylenic Scaffolding (Amber L. Sadowy and Rik R. Tykwinski).
6.1 Introduction.
6.2 Supramolecular SPMs.
6.3 Conclusions.
6.4 Experimental: Selected Procedures.
7 Supramolecular 3D Architectures by Metal-directed Assembly of Synthetic Macrocycles (Laura Pirondini and Enrico Dalcanale).
7.1 Introduction.
7.2 Coordination Cages.
7.3 Conclusion.
7.4 Experimental: Selected Procedures.
8 New Properties and Reactions in Self-assembled M6L4 Coordination Cages (Makoto Fujita and Michito Yoshizawa).
8.1 Introduction.
8.2 Self-assembly of Hollow Complexes.
8.3 Inclusion Properties.
8.4 New Physical Properties.
8.5 New Reactions.
8.6 Conclusion.
8.7 Experimental: Synthesis of M6L4 Cage 2.
9 Anion-binding Macrocycles (Evgeny A. Katayev, Patricia J. Melfi, and Jonathan L. Sessler).
9.1 Introduction.
9.2 Ditopic Receptors and Receptors for Ion Pairs.
9.3 Receptors with Different Binding Sites.
9.4 Conclusions.
9.5 Experimental: Selected Procedures.
10 Rotaxane and Catenane Synthesis (James A. Wisner and Barry A. Blight).
10.1 Introduction.
10.2 Macrocyclization Reactions Resulting in Interlocked Products.
10.3 Conclusions.
10.4 Experimental: Selected Procedures.
Index
