 Nitroxides: Applications in Chemistry, Biomedicine, and Materials Science
ISBN: 978-3-527-31889-6
Hardcover
438 pages
April 2008
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Symbols and Abbreviations.
1 Fundamentals of Magnetism (Jun Yamauchi).
1.1 Magnetism of Materials.
1.2 Origins of Magnetism.
1.3 Temperature Dependence of Magnetic Susceptibility.
1.4 Experimental Magnetic Data Acquisition.
2 Molecular Magnetism (Jun Yamauchi).
2.1 Magnetic Origins from Atoms and Molecules.
2.2 Characteristics of Molecular Magnetism.
2.3 Nitroxide as a Building Block.
2.4 Low-Dimensional Properties of Nitroxides.
3 Fundamentals of Electron Spin Resonance (ESR) (Jun Yamauchi).
3.1 Magnetic Resonance of Electron and Nuclear Spins.
3.2 Principle of Electron Spin Resonance (ESR).
3.3 Anisotropic Parameters in Crystal.
3.4 Pulsed ESR.
3.5 Double Resonance.
3.6 ESR of Magnetic Materials.
4 Recent Advantages in ESR Techniques Used in Nitroxide Applications (Alex I. Smirnov).
4.1 Introduction.
4.2 Macromolecular Distance Constraints from Spin-Labeling Magnetic Resonance Experiments.
4.3 Multiquantum ESR.
4.4 Spin-Labeling ESR of Macroscopically Aligned Lipid Bilayers and Membrane Proteins.
4.5 Spin-labeling ESR at High Magnetic Fields.
5 Preparations, Reactions, and Properties of Functional Nitroxide Radicals (Shin’ichi Nakatsuji).
5.1 Short Historical Survey and General Preparative Methods of NRs.
5.2 Early Progress toward FNRs for Organic Magnetic Materials.
5.3 Organic Ferromagnets Based on NRs.
5.4 Charge-Transfer Complexes/Radical Ion Salts Based on NR.
5.5 Donors and Acceptors Carrying NRs and the Derived CT Complexes/Radical Salts.
5.6 Suprampolecular Spin Systems Carrying NRs.
5.7 Photochromic Spin Systems Carrying NRs.
5.8 FNRs for Biomedicinal Applications.
5.9 Functional Nitrones.
5.10 Conclusion.
6 Nitroxide Spin Probes for Studies of Molecular Dynamics and Microstructure (Gertz I. Likhtenshtein).
6.1 Nitroxide Molecular Dynamics.
6.2 The Spin Label–Spin Probe Methods.
6.3 Spin Oximetry.
6.4 Determination of the Immersion Depth of Radical and Flourescent Centers.
6.5 Nitroxide as Polarity Probes.
6.6 Electrostatic Effects in Molecules in Solutions.
6.7 Spin-Triplet–Fluorescence–Photochrome Method.
6.8 Dual Fluorophore–Nitroxide as Molecular Dynamics Probes.
6.9 Nitroxide Spin pH Probes.
6.10 Nitroxides as Spin Probes for SH Groups.
7 Nitroxide Redox Probes and Traps, Nitron Spin Traps (Gertz I. Likhtenshtein).
7.1 Nitroxide Redox Probes.
7.2 Nitron Spin Trapping.
7.3 Dual Fluorophore–Nitroxides (FNRO·) as Redox Sensors and Spin Traps.
8 Nitroxides in Physicochemistry (Gertz I. Likhtenshtein).
8.1 Polymers.
8.2 Nitroxides in Photochemistry and Photophysics.
8.3 Complexes Transition Metals with Nitroxide Ligands.
8.4 Nitroxides in Inorganic Chemistry.
9 Organic Functional Materials Containing Chiral Nitroxide Radical Units (Rui Tamura).
9.1 Introduction.
9.2 Synthesis and Structure of Chiral NRs.
9.3 Magnetic Properties of Chiral NRs in the Solid State.
9.4 Properties of Chiral NRs in the Liquid Crystalline State.
9.5 Application of Redox Properties of NRs.
9.6 Conclusion.
References.
10 Spin Labeling in Biochemistry and Biophysics (Gertz I. Likhtenshtein).
10.1 Proteins and Enzymes.
10.2 Biomembranes.
10.3 Nucleic Acids.
10.4 Polysacchrides and Dextrins.
References.
11 Biomedical and Medical Applications of Nitroxides (Gertz I. Likhtenshtein).
11.1 Cells and Tissues. Biomedical Aspects.
11.2 Nitroxides In Vivo.
11.3 Medical Application of Nitroxides.
11.4 Areas Related to Future Development of Nitroxide Applications in Biomedicine.
References.
12 Conclusion.
Index.
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