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Thermodynamic Timeline
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Antiquity |
Early ideas of atomism, heat as a mode of motion within bodies and pressure is the result of such motion, are discussed. |
ca150BC |
Hero of Alexandria writes Pneumatics,
an investigation on atmospheric air, summarizing much of
what was known at the time about siphons, pumps, the effects
of heat on liquids, and engine designs.
|
1592 |
Galileo
Galilei (1564-1642)
builds a crude thermometer (thermoscope) using the contraction
of air to draw water up a tube. |
1612 |
Santorre Santorio (1561-1636)
uses an early thermoscope, and is the first to propose a
scale for temperature. Santorre writes to Galileo including
sketches of his device, to which Galileo replies that it
was his own invention. Priority remains unclear.
|
1638 |
Galileo points
out that single-stage pumps can only raise water about 32
feet, though this had been common knowledge to pump makers
of the time. |
1641 |
Ferdinand II, Grand Duke of Tuscany (1610-1670), invents a liquid-glass thermometer with one end sealed, an improvement to Galileo's thermoscope. |
1643 |
Evangelista
Torricelli (1608-1647) invents the mercury barometer,
and produces the first partial vacuum. |
1648 |
Blaise
Pascal (1623-1662) predicts that the height achieved
by mercury in a barometer should decrease as one scales
a mountain, and this is confirmed experimentally by his
brother-in-law, Florin Perrier. |
1654 |
Otto von Guericke (1602-86)
demonstrates that two iron hemispheres held together by a
strong partial vacuum can’t be separated by a team
of horses.
|
1660 |
Robert
Boyle (1627-91) publishes New Experiments Physio-Mechanicall,
Touching the Spring of the Air, and its Effects, based
in part on experiments with his lab assistant, Robert
Hooke (1635-1703).
Richard Towneley (1628-1707) and Henry Power (1623-1668) perform further experiments establishing the PV law for expansion (the so-called "Boyle's Law" or "Marriotte's Law"). |
1661 |
Boyle responds to criticism by adding an appendix to his 1660 work, presenting improved experimental results and giving a version of what is now known as "Boyle's Law" for the case of compression. |
1663 |
Pascal writes On
the Equilibrium of Liquids (published posthumously)
suggesting that pressure is transmitted equally in all
directions in a fluid (later known as "Pascal's
law"), probably discovered around 1648.
Power's book Experimental Philosophy is published with early results on the PV law. |
1673 |
Christiaan
Huygens (1629-1695) patents but does not
build a one-shot engine using gunpowder fuel. The first
internal combustion engine?
|
1676 |
Edmé Mariotte (~1620-1684) independently finds the relationship between pressure and volume, in his work On the Nature of Air (known as "Mariotte's law" in France , and "Boyle's law" elsewhere.) |
1690 |
Denis
Papin (1647-1712)
uses steam pressure to move a piston for the first time.
The French credit Papin as the inventor of the steam engine. |
1698 |
Thomas
Savery (1650?-1715)
patents a steam pump. |
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|
1701 |
Sir
Isaac Newton (1643-1727)
suggests an oil-filled thermometer with a scale defined by
0o at the ice point
and 12o at human body temperature. |
1702 |
Guillaume Amontons (1663-1705) examines the idea of absolute zero from the observation that equal drops in temperature produce equal drops in pressure, and since pressure cannot become negative, there must be a lower limit to temperature.
Ole Christensen Rømer (1644-1710)
devises a temperature scale based on the two phenomena of
the boiling point of water and the temperature at which snow
begins to form. He makes the first measurement of the speed
of light based on astronomical observations.
|
1712 |
Thomas
Newcomen's (1663-1729) steam
engine, using power generated from atmospheric pressure
operating on a piston with condensing steam on the low
pressure side, is placed in service to pump water from
mines. |
1714 |
Gabriel
Fahrenheit (1686-1736)
devises a mercury-in-glass thermometer and introduces a temperature
scale with simple calibration to allow common measurements. |
1733 |
Daniel
Bernoulli (1700-1782), in a treatise on hydrodynamics
worked out in the period from 1728 to 1733, gives a derivation
of the gas laws from a billiard ball model, derives the Boyle-Mariotte
relation and uses conservation of mechanical energy
to show that as temperature changes the pressure will change
proportionally to the square of the particle velocities.
This text marks the first truly statistical treatment of kinetic
theory. A significantly updated edition of the text
is published in 1738. The paper is all but forgotten until
1859. |
1742 |
Anders
Celsius (1701-1744)
publishes "Observations
on two persistent degrees on a thermometer," basing
his scale on the freezing point (100 degrees) and boiling
points (0 degrees) of water. (The system is reoriented in
1745 by Carl Linnaeus,
a.k.a. Carl von Linné. |
1744 |
Mikhail
Vasilievich Lomonosov (1711-1765)
publishes a paper on the causes of heat and cold, stating
that heat is a form of motion. |
1748 |
Lomonosov formulates laws of conservation of energy and mass. Through about 1760, he performs a number of theoretical investigations about molecular structures, speculating on the effects of translation, vibration, and rotations of such molecules. |
1760-1764 |
Joseph
Black (1728-1799)
defines the difference between temperature and heat and
finds that melting ice absorbs heat without changing temperature.
He uses these results to form the basis of caloric
theory. |
1765 |
James
Watt (1736-1819)
invents his improved steam engine incorporating the external
condenser, rotary motion, and double-acting piston. The engine
is over six times more effective than Newcomen's. |
1769 |
Nicolas
Cugnot (1725-1804)
demonstrates the first steam powered vehicle in France.
He is arrested for endangering citizens. |
1772 |
Johan Carl Wilcke (1741-1811) calculates the latent heat
of ice. |
1781 |
Wilcke proposes the concept of specific
heats. |
1782 |
Antoine
Laurent Lavoisier (1743-1794)
establishes an early version of conservation of matter after finding the weights before and
after chemical reactions are equal. |
1783 |
Lavoisier publishes Reflections on Phlogiston,
pointing out the weaknesses of phlogiston theory with respect
to combustion. |
1786 |
Lavoisier and Laplace publish Memoir on Heat. |
1787 |
Jacques-Alexandre
Charles (1746-1823)
determines that for a given temperature change, different
gases expand the same amount (now known as "Charles's
law"). In 1783 he
had launched the first hydrogen balloon from Paris,
witnessed by Benjamin Franklin. |
1789 |
Lavoisier publishes Elementary
Treatise on Chemistry, which
contains the law of mass conservation. |
1794 |
Lavoisier is
guillotined during the French revolution. |
1798 |
Benjamin
Thompson (Count Rumford) (1753-1814) describes cannon-boring
experiments that demonstrate the conversion
of work into heat in Enquiry Concerning the Source
of Heat which is Excited by Friction. He also was
not able to detect an increase in weight due to heating.
Both of these results are contrary to caloric theory. In
1805 he marries Lavoisier’s
widow. |
1799 |
Sir Humphrey Davy (1778-1829) performs ice-rubbing experiments that
demonstrate the conversion of work into heat. He suggests
that an indefinite amount of heat could be generated from
a body (whereas caloric theory severely limits its available
amount).
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1801 |
Richard Trevithick (1771-1819)
builds a prototype steam powered railroad locomotive.
John
Dalton (1766-1844)
finds that two gases in the same region produce the same
pressure as if they occupied the region alone, known as the
law of partial pressures. |
1802 |
Joseph-Louis
Gay-Lussac (1778-1850)
finds that, at a given pressure, the change in volume is
proportional to the change in temperature. |
1803 |
Dalton formulates his atomic theory of matter, stating
that chemicals are formed by integer numbers of atoms, by
studying the weights of chemicals and reactants.
William
Henry (1775-1836)
finds that the mass of gas dissolved in a liquid is proportional
to the pressure of the gas (later known as "Henry's
law"). |
1805 |
Oliver
Evans (1755-1918)
demonstrates the first steam powered land vehicle and steam boat
in the US. |
1806 |
Thomas
Young (1773-1829)
formulates a precursor to the modern formulation of energy,
mathematically associating it with mv2 (twice
the modern "kinetic energy"). Young's System
of Chemistry contains the first published account
of Dalton's ideas
on atomic theory. |
1807 |
Jean
Baptiste Joseph Fourier (1768-1830)
completes his On
the Propagation of Heat in Solid Bodies, introducing
many mathematical novelties, including his series expansion
techniques. |
1808 |
Gay-Lussac states that gases chemically combine in exact
proportions of volume. |
1810 |
Sir John Leslie (1766-1832) produces ice by absorbing water
into sulfuric acid to produce a vacuum. |
1811 |
Siméon-Denis Poisson (1781-1840) develops his mathematical
theory of heat, based on the work of Fourier.
Amedev
Avogadro (1776-1856)
hypothesizes that all gases of a given volume have the same
number of molecules, regardless of pressure or temperature
("Avogadro's law"). |
1812 |
Davy writes Elements of Chemical Philosophy,
including a hypothesis that in addition to the vibrational
and undulatory motion of solids, gases also exhibit rotational
motion about an axis.
Delaroche and Bérard measure
the specific heats of a large number
of gases at atmospheric pressure. Their measurements agree with Laplace's predictions and remain a cornerstone for caloric theory. |
1814 |
George
Stephenson (1781-1848)
builds the first practical steam powered railroad locomotive,
the Blutcher,
for the Killingworth Colliery. |
1816 |
John Herapath (1790-1868) writes On the Physical Properties
of Gases, essentially proposing the same theory as
that of Daniel
Bernoulli, but developed independently.
Robert
Stirling (1790-1878) patents a practical heat engine using air as
the working fluid. |
1821 |
Thomas Johann Seebeck (1770-1831) discovers that heat
is converted into electricity in the junction of some metals,
known as thermoelectricity. |
1822 |
Fourier's
essay Theorie
Analytique de la Chaleur (Analytic
Theory of Heat) is published, furthering his analytical techniques
and formally introducing the use of dimensions for physical
quantities.
Charles Cagniard de la Tour (1777-1859), in liquefaction
experiments, finds that both temperature and pressure must
be appropriately controlled, and discovers that substances
have a critical point. |
1824 |
Sadi
Carnot (1796-1832)
publishes "Reflections on the
Motive Power of Fire," introducing ideal gas cycle
analysis, showing that when heat passes between two bodies,
thermodynamic work (which he defines) is done, and proposes
an idea for an internal combustion engine. His treatise
includes the concept of a thermodynamic cycle and the principle that the
efficiency of a reversible cyclic engine operating between
two heat reservoirs depends only on the temperatures of
the reservoirs and not on the working substance.
Pierre-Simon
Laplace (1749-1827) publishes several papers refining
an idea of Newton's
that gases are formed through repulsive interactions. |
1826 |
John
Ericsson (1803-1869) invents the shell-and-tube heat
exchanger for use as a condenser in steam ships. |
1829 |
Gustave-Gaspard Coriolis (1792-1843) defines the term "kinetic
energy" in his studies published as On the Calculation
of Mechanical Action.
Stephenson wins the Rainhill Trials
for the Liverpool and Manchester Railway with the Rocket,
triggering widespread adoption of steam locomotives. |
1834 |
Emile
Clapeyron (1799-1864)
formulates the first version of the Second Law of Thermodynamics,
based on studies of steam engines.
Jacob Perkins (1766-1849) patents and produces first vapor-compression
refrigeration machine. |
1842 |
Julius
Robert Mayer (1814-1878)
clearly formulates the conservation of energy, and proposes
that heat is a form of (mechanical) energy.
William
Thomson (Lord Kelvin) (1824-1907)
publishes On the Uniform Motion
of Heat in Homogeneous Solid Bodies. |
1843-1848 |
Through a careful series of experiments, James
Prescott Joule (1818-1889)
establishes the exact relationship between heat and mechanical
work.
John James Waterston (1811-1883) anonymously
publishes Thoughts on the Mental Functions (1843)’ A
note at the end contains a full and accurate account of the
kinetic theory of gases and the idea of a mean free path.
The work goes all but completely unread. |
1845 |
Waterston submits a paper on the kinetic theory of gases
with the same title as his 1843 book to the Royal Society,
which rejects it. The paper lays out the ideas of energy
equipartition and gives the first modern kinetic definition
of temperature. A short abstract appears a year later, and
again in 1851, but the work is ignored. |
1847 |
Joule publishes "On Matter, Living Force, and Heat" in
the Manchester Courier, stating the principle of
the conservation of energy and giving the conversion factor
from heat to kinetic energy (the “mechanical equivalent
of heat”).
Hermann
Ludwig Ferdinand von Helmholtz (1821-94)
publishes his On the Conservation
of Energy, extending Carnot's
principle of the 'impossibility of unlimited moving force' (kinetic
energy) to a mathematical formulation of the 'principle of conservation of
living force' (vis viva / kinetic energy). His work is independent of Joule's
publications.
John William Draper (1811-1882) finds
that all substances begin to glow around 525°C, starting in the red and
eventually becoming white. |
1848 |
Joule reads
a paper using Herapath's kinetic
theory. The paper contains the first numerical results from
the kinetic theory. The paper is not published until 1851,
and not well known until Clausius's reference to it in 1857.
William
John Macquorn Rankine (1820-1872)
carries out research into mechanics and heat (mainly through 1855). William
Thomson develops
a scale of absolute temperature (now known as the "Kelvin" scale)
based on the theory of Carnot. |
1849 |
James
Thomson (1822-1892),
using Carnot's
theories, predicts the reduction of the freezing point of
water under high pressures.
William
Thomson,
in speaking of Carnot's theory, coins the terms “mechanical
energy” and "thermodynamics." |
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|
1850 |
Rudolf
Clausius (1822-88)
gives a verbal formulation of the Second
Law, stating that
there is no mechanism whose only function is the transfer
of heat, and is probably the first to see that there were
two basic principles: the First and Second laws of thermodynamics.
He introduces the concept of U, which
we now call the internal energy, and later assigns the symbol S to entropy.
Ericsson
demonstrates a large hot air engine based on the heat engine
cycle now bearing his name. |
1851 |
William
Thomson independently
rediscovers the idea of absolute zero (149 years after Amontons),
extrapolating from Charles' law that it must be about -273°C,
and suggesting that the energy of the molecules would tend
to zero. He also derives the second law of thermodynamics
using Carnot's ideas. |
1852 |
James
Joule and Lord
Kelvin demonstrate
that a rapidly expanding gas cools. Kelvin gives the first general
statement of the principle of the "universal tendency toward
dissipation of energy."
Henri-Victor Regnault (1810-1878)
shows that gas behavior doesn't quite follow Boyle's law at low
temperatures and extrapolates a value of -273°C for absolute
zero. |
1853 |
Rankine defines heat engine efficiency. |
1854 |
Clausius proposes the function dQ/T as a way to compare
heat flows with heat conversions.
Rankine introduces
the P-v diagram and relates it to work. |
1855 |
Rankine publishes Outlines
of the Science of Energetics. |
1857 |
Clausius publishes
a paper on a mathematical kinetic theory, explaining evaporation
and establishing heat as energy distributed statistically
among particles. |
1858 |
Clausius introduces the idea of the mean free path of
a particle in working out a kinetic theory of diffusion.
Isambard
Kingdom Brunel (1806-1859)
designs and launches the steam powered Great Eastern,
which remains the largest ship built until the Mauritania in
1905. |
1859 |
James
Clerk Maxwell (1831-79)
reads a paper on kinetic theory, printed in 1860 as "Illustrations
of the Dynamical Theory of Gases," using random velocity
distributions for gases, and showing viscosity to be independent
of temperature. The paper is originally intended to show
internal inconsistencies in the kinetic theory, but through
its rigor it greatly refined the theory and provided new
insights.
Bernoulli's paper
of 1733 is republished due to renewed interest in kinetic
theory.
Herapath henceforth goes into obscurity.
Rankine publishes the first text on thermodynamics for
engineers. |
1860 |
Michael
Faraday(1791-1867)
wrote in his paper "Pressure Melting
Effect" that the freezing point
of water decreases with increasing pressure.
Maxwell shows
a discrepancy between the prediction by kinetic theory
and experiment of the specific heat of diatomic gases.
The discrepancy is not resolved satisfactorily until
the early stages of quantum theory. This paper is the
first of four works on kinetic theory by Maxwell, bringing
a new level of rigor and sophistication to the theory. |
1861 |
Thomas Andrews (1813-1885), in a series of experiments
with CO2 through 1869, finds that at low temperatures Boyle's
law breaks down, and there are regions on a PV chart where,
for a given isotherm, changes in volume produce no change
in pressure. This region is recognized to be the liquid-vapor
equilibrium state. He rigorously finds the critical point and triple point. |
1862 |
Jean
Lenoir (1822-1900) constructs an automobile using
a double-acting, electric spark-ignition internal combustion
engine fueled by coal gas. In 1863, Lenoir attached an improved
engine (using petroleum and a primitive carburetor) to a
three-wheeled wagon and manages to complete an historic fifty-mile
road trip. |
1863 |
John Tyndall (1820-1893) publishes Heat as a Mode
of Motion, popularizing Maxwell's
ideas on heat.
Andrews shows that, contrary to expectations, above a substance's
critical point there is a continuous change from gas to liquid
and vice versa through variations of temperature and pressure. |
1865 |
Clausius uses Carnot's
techniques to derive "entropy", a term coined for the quantity dQ/T defined earlier by him. He shows the two
laws of thermodynamics are expressible in the same ways as
in the older caloric theory. In a public speech entitled "The
entropy of the universe tends to a maximum," he shows
how thermodynamics seems to imply an eventual heat death
for the universe. Clausius states the first and second laws
of thermodynamics in two lines:
- The energy of the universe
is constant.
- The entropy of the universe tends toward
a maximum.
|
1867 |
Maxwell publishes
his major work on kinetic theory, On the Dynamical Theory
of Gases. Maxwell's work spurs serious debates on the
statistical interpretation of irreversibility.
Nikolaus
Otto (1832-1891)
demonstrates the first practical two-stroke internal combustion
engine at the Paris World’s Fair. |
1868 |
Ludwig
Boltzmann (1844-1906)
extends Maxwell's distribution law to include external forces.
In the case of gravity, he works through the distribution
of densities and pressures and shows that thermal equilibrium
is maintained. |
1871 |
Maxwell,
helping out P.
G. Tait, who was drafting a textbook
on thermodynamics, outlines his parable of the daemon to
conceptually explain the statistics of energy carried by
gas molecules.
Boltzmann suggests
that one may derive the probabilistic picture from the
kinetic one by heuristically assuming that all microstates
must be realized in a system before returning to a specific
microstate, and thus measured values should average the
effects of such states.
James
Thomson suggests that even
below the critical point, a substance may smoothly transition
between gas and liquid from considerations of experimental
data on pressure and volume. |
1872 |
Boltzmann states the Boltzmann equation for the temporal
development of distribution functions in phase space, and
derives his H -Theorem, showing explicitly that isolated
systems must always evolve in such a way that entropy increases.
He introduces a number of mathematical innovations, including
a technique of discretizing the allowed energy levels for
a molecule, and allowing this energy bin to go to zero. The
paper meets with wide-spread opposition.
George
Bailey Brayton (1830-1892)
receives a patent for his oil-fired engine. The thermodynamic
cycle is identical to that of the present gas turbine engine. |
1873 |
Josiah
Willard Gibbs (1839-1903)
publishes Graphical
Methods in the Thermodynamics of Fluids and A
Method of Geometrical Representation of the Thermodynamic
Properties of Substances by Means of Surfaces, introducing
many new graphical techniques. From 1873 to 1878 he publishes
a series of important articles in the Transactions
of the Connecticut Academy of Arts and Sciences, widely
influencing scientists in the US and in Europe .
Johannes
Diderik van der Waals (1837-1923),
in his doctoral dissertation, gives the first correct approximation for the effects
of a non-vanishing ratio of molecule diameter to average distance by assuming
long-range attractive and short-range repulsive forces, applying this to the
case of gases at high densities. Using his "equation of state," he
provides the first successful explanation of a gas-liquid phase transition. The
theory accounts for Andrews's critical point phenomena and confirms James Thomson's
hypothesis. |
1874 |
William
Thomson points out that the irreversibility of
Boltzmann's kinetic theory seems to contradict the underlying
classical laws of physics remaining time-invariant (the so-called "reversibility
paradox," sometimes attributed to Loschmidt). He formally
states the Second Law of Thermodynamics. |
1876 |
Gibbs publishes the first part of On the Equilibrium
of Heterogeneous Substances (the 2nd part in 1878).
The works deal with chemical reactions, phase equilibrium
and the use of free energy, and includes the
important concept of chemical potential.
Karl Paul Gottfried von Linde (1842-1934)
builds the first practical refrigerator using liquid ammonia.
Otto improves
his engine to operate on the four-stroke “Otto
cycle.” |
1879 |
Josef
Stefan (1835-1893)
observes from experiments on cooling rate of bodies that
the total radiant flux from a blackbody is proportional to
the fourth power of its temperature and states the Stefan-Boltzmann
law.
Gottlieb
Daimler (1834-1900)
patents the multicylinder engine using a common crank. |
1884 |
Boltzmann derives
the Stefan-Boltzmann blackbody radiant flux
law from thermodynamic considerations.
Gibbs coins
the term "statistical
mechanics" for the kinetic
theory's treatment of thermodynamic issues.
Daimler produces
practical automotive engine. |
1888 |
Henri-Louis Le Chatelier (1850-1936) states that
the response of a chemical system perturbed from equilibrium
will be to counteract the perturbation. |
1893 |
Rudolph
Diesel (1858-1913)
demonstrates an oil-fueled engine that uses the high temperature caused by compression to initiate combustion (compression ignition). He nearly dies from an
engine explosion. |
1895 |
von Linde succeeds in liquefaction of air. |
1896 |
The Swedish chemist Svante
Arrhenius (1859-1927) predicts that the increasing
rate at which fossil fuels are being combusted will increase
the atmosphere's carbon dioxide concentration and lead
to warming, a theory now known as global
warming. (Also see 1997 and 2005 Kyoto Protocol
entries). |
1897 |
Max Karl Ernst Ludwig Planck (1858-1947) states the Second
Law of Thermodynamics as: "It is impossible to construct
an engine which, working in a complete cycle, will produce
no effect other than the raising of a weight and the cooling
of a heat reservoir."
Diesel demonstrates
a practical engine.
Charles
A. Parsons (1854-1913)
demonstrates a practical steam turbine in the ship Turbinia. |
1899 |
Emile
Hilaire Amagat (1841-1915)
publishes The Laws
of Gases containing the results from extensive experiments on gases under
very high pressures. |
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|
1900 |
Planck, studying blackbody
radiation and following Boltzmann's techniques
of dividing the energy continuum into cells, proposes fixing
cell sizes to be proportional to oscillator frequency, and
in so doing derives the correct radiation spectrum for blackbodies.
Planck proposes the constant, h (Planck's
constant), as a quantum of action in phase space.
Production in the US of internal combustion powered automobiles
(936) is still outweighed by steam (1681) and electric (1575)
powered vehicles. |
1902 |
Gibbs publishes Elementary Principles in Statistical
Mechanics, his treatise on the subject, giving his
full account of ensemble theory and their relationships
(including the so-called "Gibbs paradox," though
there was nothing paradoxical about it at the time). |
1903 |
Orville Wright (1871-1948)
and Wilbur Wright (1867-1912)
successfully fly the first powered airplane. |
1905 |
Albert
Einstein (1879-1955)
publishes a paper on the photoelectric effect, basing his
analysis on an analog of the statistical mechanical approach
for classical electromagnetic fields modeled as quanta of
light. From this time, the major work in thermodynamics shifts
from classical to quantum-based approaches. |
1906 |
Walther
Nernst (1864-1941)
formulates his "heat theorem," stating
that in the limit of absolute zero temperature, both the
entropy change and the heat capacity go to zero (subsequently
recognized as the Third Law of Thermodynamics). |
1908 |
Planck begins
formulating derivations of the black-body law starting with
an assumption of energy quantization.
Henry
Ford (1863-1947)
develops the assembly line method of automobile manufacturing |
1909 |
Constantin
Carathéodory (1873-1950) publishes a purely
mathematical and axiomatic account of thermodynamics. |
1911 |
Planck's first paper explicitly quantizing the allowed
radiation of oscillators in a blackbody is published.
Otto Sackur (1880-1914)
suggests the need for an absolute definition of entropy,
in order that quantum systems be taken into account.
Heike
Kamerlingh Onnes (1853-1926) experimentally finds that
mercury will become superconductive when cooled very close
to absolute zero and also discovers superfluidity.
Nernst's
experiments with many substances and shows specific heats
going to zero at absolute zero in general. The results provide strong
support for the new quantum theories. |
1912 |
Sackur and Hugo
Tetrode (1895-1931) independently solve
Boltzmann's Law and show a need for quantization in classical
gas laws. |
1916 |
Sydney Chapman (1888-1970) and David
Enskog (1884-1947)
systematically develop a kinetic theory of gases. |
1919 |
James
Jeans (1877-1946)
discovers that the dynamical constants of motion determine
the distribution function for a system of particles. |
1922 |
Louis
Victor Pierre Raymond duc de Broglie (1892-1987)
applies Sackur's technique
of quantizing phase space to derive the Wien distribution
law for energy density. |
1923 |
Gilbert
Newton Lewis (1875-1946)
publishes Thermodynamics
and the Free Energy of Chemical Substances, coordinating
the understanding of thermodynamics and chemistry. |
1925 |
Einstein,
citing works by Bose and de Broglie, suggests that the analogy
between quantum gases and molecular gases is complete, and
that both photons and molecules have both particle and wave
characteristics. |
1926 |
Robert
Hutchings Goddard (1882-1945)
launches the first rocket, which uses liquid fuel and reaches
a height of 184 feet and speed of 60 miles per hour. |
1929 |
Frank
Whittle (1907-1996)
submits a term paper establishing the basis for turbojet
engines by reproducing the Brayton cycle as applied to turbines
rather than piston engines. |
1931 |
R-12 is introduced as a commercial refrigerant. At the time R-12 is hailed as a significant advancement over other refrigerants because it is non-toxic, non-flammable, stable and has great thermodynamic characteristics. (Note: See 1987 R-12 entry) |
1939 |
First flight of a turbojet-powered aircraft using an engine
design by Hans
von Ohain (1911-1998). |
1941 |
First flight of turbojet aircraft based on Whittle's engine.
Whittle was unaware of von
Ohain's work. |
1942 |
V2 rocket covers a distance of 200 km. |
1947 |
First supersonic flight by Maj.
Charles Elwood (Chuck) Yeager (1923-
) in the Bell X-1 aircraft. |
1957 |
Sputnik 1, the first man-made satellite is launched into
orbit |
1961 |
Vostok 1, the first manned space mission, makes 2 orbits
around the earth with astronaut Yuri
Gagarin (1934-1968). |
1969 |
First manned mission to the Moon in spacecraft Apollo
11, with astronauts Michael
Collins (1930 - ) who remained
aboard the command module in lunar orbit while Neil
Armstrong (1930-
) and Edwin
(Buzz) Aldrin (1930-
) landed on the Moon. |
1981 |
First flight of the space shuttle. |
1987 |
The International Ozone Trends Panel concludes R-12 and other CFC refrigerants destroy the earth's ozone layer. An agreement is reached to phase out production of R-12. The race is on to find a suitable replacement. (Also see 1931 R-12 entry) |
1995 |
The world's first volume production hybrid electric vehicle (Toyota Prius) is introduced to the Japanese market. |
1997 |
The Kyoto Protocol is
adopted, which calls for nations to reduce their carbon dioxide
emissions. The Kyoto Protocol must still be ratified by countries
before it goes into effect. (See 1896 Svante
Arrhenius and 2005 Kyoto
Protocol entries). |
1999 |
Icelandic New Energy formed with a mission "to
investigate the potential for eventually
replacing the use of fossil fuels in
Iceland with hydrogen based fuels
and create the world´s first hydrogen
economy." The company is a joint venture between the Icelandic Government, Shell Hydrogen, Norsk Hydro and DaimlerChrysler.
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2002 |
The Japanese government begins leasing fuel-cell powered vehicles from Honda and Toyota. The cost of the lease is approximately 40 times more than a lease for a conventional car. |
2003 |
A combined-cycle power plant designed to break the 60% efficiency barrier is installed at the Baglan Bay Power Station in Cardiff,
Wales, United Kingdom by General Electric.
|
2004 |
June 21: SpaceShipOne, designed by Burt Rutan and piloted by Michael Mevill, becomes the first non-government-funded craft to enter space. After landing, Mevill holds up the sign "SpaceShipOne - Government Zero."
Diesel versus Gasoline: 45% of all new cars sold in Europe are diesel, up from 22% in 1998. Less than 0.5% of all new cars sold in the United States are diesel. Diesel cars emit less CO2 (a gas linked to global warming) and use less fuel while gasoline cars emit less pollution (e.g., NOX, SOX, and particulates).
|
2005 |
Hybrid electric vehicles (HEVs) offered by the following manufacturers in the United States: Chevrolet, Dodge, Ford, GMC, Honda, Lexus, and Toyota. More manufacturers plan to begin production of HEVs in the coming years.
China replaces the world's last long-distance steam-powered train with a diesel locomotive. China intends to build 30 new nuclear reactors by 2020 in response to growing air pollution problems and a surging demand for electricity.
Wind turbines generate approximately 20% of Denmark's and less than 1% of the United States' electricity.
February 16: The Kyoto Protocol comes
into force limiting the emission of greenhouse gases believed
to cause global warming. The protocol applies to the approximately
140 countries that ratified the treaty, which account for
more than 55% of the world's greenhouse gas emissions. The
United States, which is the world's largest producer of greenhouse
gases, did not ratify the treaty because it feels the treaty
is flawed. (See 1896 Svante
Arrhenius and 2005 Kyoto
Protocol entries).
A family in California is the first to lease a fuel cell powered car. The family pays $500/month to lease the $1 million car. |
2006 |
September: The Wärtsilä RTA96-C, a 109,000 hp turbocharged 2-stroke Diesel engine, is first put into service (for comparison, car engines typically produce 100-300 hp). The engine is designed for large container ships, has 14 cylinders, stands 13.5 m tall (~40 ft), is 27 m long (~ 85 ft), weighs over 2300 tons and has a cycle thermal efficiency of 50%.
BMW presents a hydrogen powered internal combustion engine at the Los Angeles Auto Show. BMW sees this as a possible alternative to hydrogen powered fuel cells and gasoline powered internal combustion engines.
Due to concerns over global warming and energy security, venture capitalists in the US are increasingly seeing the potential to make large profits by investing in small companies developing alternative energy technologies. Investments by US venture capitalists in energy technology companies increased from approximately $0.5 million in 2004 to $2 billion in 2006, and now represent approximately 9% of all US venture capital investments. Venture capitalists invest in small companies with big ideas and sound business plans and help them to grow very fast by providing business expertise. For example, the explosive growth of both Google and YouTube were supported by venture capitalists.
California passes a law requiring 25% reduction in greenhouse emissions by 2020. Advocates hope this will make California a leader in low-carbon energy technologies that it can sell to other states and countries. Opponents think the law will make energy too expensive in California and cause companies to leave the state. |
2008 |
GM plans to deploy 100 fuel cell powered cars. |
2010 |
Ballard plans to begin producing a commercially viable fuel cell for cars. |
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