|
Ac
|
acetyl
|
|
acac
|
acetylacetonate
|
|
AIBN
|
2,2Õ-azobisisobutyronitrile
|
|
Ar
|
aryl
|
|
BBN
|
borabicyclo[3.3.1]nonane
|
|
BCME
|
bis(chloromethyl) ether
|
|
BHT
|
butylated hydroxytoluene (2,6-di-t-butyl-p-cresol)
|
|
BINAL-H
|
2,2Õ-dihydroxy-1,1Õ-binaphthyllithium aluminum hydride
|
|
BINAP
|
2,2Õ-bis(diphenylphosphino)-1,1Õ-binaphthyl
|
|
BINOL
|
1,1Õ-bi-2,2Õ-naphthol
|
|
bipy
|
2,2Õ-bipyridyl
|
|
BMS
|
boranedimethyl sulfide
|
|
Bn
|
benzyl
|
|
Boc
|
t-butoxycarbonyl
|
|
BOM
|
benzyloxymethyl
|
|
bp
|
boiling point
|
|
Bs
|
brosyl (4-bromobenzenesulfonyl)
|
|
BSA
|
N,O-bis(trimethylsilyl)acetamide
|
|
Bu
|
n-butyl
|
|
Bz
|
benzoyl
|
|
CAN
|
cerium(IV) ammonium nitrate
|
|
Cbz
|
benzyloxycarbonyl
|
|
CDI
|
N,NÕ-carbonyldiimidazole
|
|
CHIRAPHOS
|
2,3-bis(diphenylphosphino)butane
|
|
Chx
|
=Cy
|
|
cod
|
cyclooctadiene
|
|
cot
|
cyclooctatetraene
|
|
Cp
|
cyclopentadienyl
|
|
CRA
|
complex reducing agent
|
|
CSA
|
10-camphorsulfonic acid
|
|
CSI
|
chlorosulfonyl isocyanate
|
|
Cy
|
cyclohexyl
|
|
d
|
density
|
|
DABCO
|
1,4-diazabicyclo[2.2.2]octane
|
|
DAST
|
N.N-diethylaminosulfur trifluoride
|
|
dba
|
dibenzylideneacetone
|
|
DBAD
|
di-t-butyl azodicarboxylate
|
|
DBN
|
1,5-diazabicyclo[4.3.0]non-5-ene
|
|
DBU
|
1,8-diazabicyclo[5.4.0]undec-7-ene
|
|
DCC
|
N,NÕ-dicyclohexylcarbodiimide
|
|
DCME
|
dichloromethyl methyl ether
|
|
DDO
|
dimethyldioxirane
|
|
DDQ
|
2,3-dichloro-5,6-dicyano-1,4-benzoquinone
|
|
de
|
diastereomeric excess
|
|
DEAD
|
diethyl azodicarboxylate
|
|
DET
|
diethyl tartrate
|
|
DIBAL
|
diisobutylaluminum hydride
|
|
DIEA
|
=DIPEA
|
|
DIOP
|
2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane
|
|
DIPEA
|
diisopropylethylamine
|
|
diphos
|
=dppe
|
|
DIPT
|
diisopropyl tartrate
|
|
DMA
|
dimethylacetamide
|
|
DMAD
|
dimethyl acetylenedicarboxylate
|
|
DMAP
|
4-(dimethylamino)pyridine
|
|
DME
|
1,2-dimethoxyethane
|
|
DMF
|
dimethylformamide
|
|
dmg
|
dimethylglyoximato
|
|
DMPU
|
N,NÕ-dimethylpropyleneurea
|
|
DMS
|
dimethyl sulfide
|
|
DMSO
|
dimethyl sulfoxide
|
|
DMTSF
|
dimethyl(methylthio)sulfonium tetrafluoroborate
|
|
dppd
|
1,4-bis(diphenylphosphino)butane
|
|
dppe
|
1,2-bis(diphenylphosphino)ethane
|
|
dppf
|
1,1Õ-bis(diphenylphosphino)ferrocene
|
|
dppp
|
1,3-bis(diphenylphosphino)propane
|
|
DTBP
|
Di-t-butyl peroxide
|
|
EDA
|
ethyl diazoacetate
|
|
EDC
|
1-ethyl-3-(3-dimethylaminopropyl)carbodimide
|
|
EDCI
|
=EDC
|
|
ee
|
enantiomeric excess
|
|
EE
|
1-ethoxyethyl
|
|
Et
|
ethyl
|
|
ETSA
|
ethyl trimethylsilylacetate
|
|
EWG
|
electron withdrawing group
|
|
Fc
|
ferrocenyl
|
|
Fmoc
|
9-fluorenylmethoxycarbonyl
|
|
fp
|
flash point
|
|
Hex
|
n-hexyl
|
|
HMDS
|
hexamethyldisilazane
|
|
HMPA
|
hexamethylphosphoric triamide
|
|
HOBt
|
1-hydroxybenzotriazole
|
|
HOBT
|
=HOBt
|
|
HOSu
|
N-hydroxysuccinimide
|
|
Im
|
imidazole (imidazolyl)
|
|
Ipc
|
isopinocampheyl
|
|
IR
|
infrared
|
|
KHDMS
|
potassium hexamethyldisilazide
|
|
LAH
|
lithium aluminum hydride
|
|
LD50
|
dose that is lethal to 50% of test subjects
|
|
LDA
|
lithium diisopropylamide
|
|
LDMAN
|
lithium 1-(dimethylamino)naphthalenide
|
|
LHMDS
|
=LiHMDS
|
|
LICA
|
lithium isopropylcyclohexylamide
|
|
LiHMDS
|
lithium hexamethyldisilazide
|
|
LiTMP
|
lithium 2,2,6,6-tretramethylpiperidide
|
|
LTMP
|
=LiTMP
|
|
LTA
|
lead tetraacetate
|
|
lut
|
lutidine
|
|
m-CPBA
|
m-chloroperbenzoic acid
|
|
MA
|
maleic anhydride
|
|
MAD
|
methylaluminum bis(2,6-di-t-butyl-4-methylphenoxide)
|
|
MAT
|
methylaluminum bis(2,4,6-tri-t-butylphenoxide)
|
|
Me
|
methyl
|
|
MEK
|
methyl ethyl ketone
|
|
MEM
|
(2-methoxyethoxy)methyl
|
|
MIC
|
methyl isocyanate
|
|
MMPP
|
magnesium monoperoxyphthalate
|
|
MOM
|
methoxymethyl
|
|
MoOPH
|
oxodiperoxomolybdenum(pyridine)(hexamethylphosphoric
triamide)
|
|
mp
|
melting point
|
|
MPM
|
=PMB
|
|
Ms
|
mesyl (methanesulfonyl)
|
|
MS
|
mass spectrometry; molecular sieves
|
|
MTBE
|
methyl t-butyl ether
|
|
MTM
|
methylthiomethyl
|
|
MVK
|
methyl vinyl ketone
|
|
n
|
refractive index
|
|
NaHDMS
|
sodium hexamethyldisilazide
|
|
Naph
|
naphthyl
|
|
NBA
|
N-bromoacetamide
|
|
nbd
|
norbornadiene (bicyclo[2.2.1]hepta-2,5-diene)
|
|
NBS
|
N-bromosuccinimide
|
|
NCS
|
N-chlorosuccinimide
|
|
NIS
|
N-iodosuccinimide
|
|
NMO
|
N-methylmorpholine N-oxide
|
|
NMP
|
N-methyl-2-pyrrolidinone
|
|
NMR
|
nuclear magnetic resonance
|
|
NORPHOS
|
bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene
|
|
Np
|
=Naph
|
|
PCC
|
pyridinium chlorochromate
|
|
PDC
|
pyridinium dichromate
|
|
Pent
|
n-pentyl
|
|
Ph
|
phenyl
|
|
phen
|
1,10-phenanthroline
|
|
Phth
|
phthaloyl
|
|
Piv
|
pivaloyl
|
|
PMB
|
p-methoxybenzyl
|
|
PMDTA
|
N,N,NÕ,NÕÕ,NÕÕ-pentamethyldiethylenetriamine
|
|
PPA
|
polyphosphoric acid
|
|
PPE
|
polyphosphate ester
|
|
PPTS
|
pyridinium p-toluenesulfonate
|
|
Pr
|
n-propyl
|
|
PTC
|
phase transfer catalyst/catalysis
|
|
PTSA
|
p-toluenesulfonic acid
|
|
py
|
pyridine
|
|
RAMP
|
(R)-1-amino-2-(methoxymethyl)pyrrolidine
|
|
rt
|
room temperature
|
|
salen
|
bis(salicylidene)ethylenediamine
|
|
SAMP
|
(S)-amino-2-(methoxymethyl)pyrrolidine
|
|
SET
|
single electron transfer
|
|
Sia
|
siamyl (3-methyl-2-butyl)
|
|
TASF
|
tris(diethylamino)sulfonium difluorotrimethylsilicate
|
|
TBAB
|
tetrabutylammonium bromide
|
|
TBAF
|
tetrabutylammonium fluoride
|
|
TBAD
|
=DBAD
|
|
TBAI
|
tetrabutylammonium iodide
|
|
TBAP
|
tetrabutylammonium perruthenate
|
|
TBDMS
|
t-butyldimethylsilyl
|
|
TBDPS
|
t-butyldiphenylsilyl
|
|
TBHP
|
t-butyl hydroperoxide
|
|
TBS
|
=TBDMS
|
|
TCNE
|
tetracyanoethylene
|
|
TCNQ
|
7,7,8,8-tetracyanoquinodimethane
|
|
TEA
|
triethylamine
|
|
TEBA
|
triethylbenzylammonium chloride
|
|
TEBAC
|
=TEBA
|
|
TEMPO
|
2,2,6,6-tetramethylpiperidinoxyl
|
|
TES
|
triethylsilyl
|
|
Tf
|
triflyl (trifluoromethanesulfonyl)
|
|
TFA
|
trifluoroacetic acid
|
|
TFAA
|
trifluoroacetic anhydride
|
|
THF
|
tetrahydrofuran
|
|
THP
|
tetrahydropyran; tetrahydropyranyl
|
|
Thx
|
thexyl (2,3-dimethyl-2-butyl)
|
|
TIPS
|
triisopropylsilyl
|
|
TMANO
|
trimethylamine N-oxide
|
|
TMEDA
|
N,N,NÕ,NÕ-tetramethylethylenediamine
|
|
TMG
|
1,1,3,3-tetramethylguanidine
|
|
TMS
|
trimethylsilyl
|
|
Tol
|
p-tolyl
|
|
TPAP
|
tetrapropylammonium perruthenate
|
|
TBHP
|
t-butyl hydroperoxide
|
|
TPP
|
tetraphenylporphyrin
|
|
Tr
|
trityl (triphenylmethyl)
|
|
Ts
|
tosyl (p-toluenesulfonyl)
|
|
TTN
|
thallium(III) nitrate
|
|
UHP
|
ureahydrogen peroxide complex
|
|
Z
|
=Cbz
|
