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Spectra Fragmentation Photonated Peptidese Plasma Chemistry Metabolites Complexes Proteins Proteomics Assisted-Laser-Desorption/Ionization Liquid-Chromatography Identification Collision-Induced Dissociation Oligosaccharides Urine Matrix Amino-Acids GC-MS Quadropole Ion-Trap Quantification Mechanism Electrospray Ionization Ionization MALDI Tandem Mass-Spectrometry Peptides Derivatives Gas-Chromatography Performance Liquid-Chromatography Peptide