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Metallocene-based Polyolefins, Preparation, Properties, and Technology, Volume 1

ISBN: 978-0-471-99911-9 November 1999 560 Pages

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The manufacture of polyolefins by metallocene catalysts represents a revolution in the polymer industry. The first, patent for a metallocene catalyst was filed in 1980 but it has been the last five years that have seen a dramatic increase in the volume of research into metallocenes and the maturing of metallocene technology. With contributions from leading experts from the US, Canada, Italy, Scandinavia, Germany and Japan, Metallocene-based Polyolefins gives comprehensive coverage of all areas of metallocene technology: catalyst structure, comonomer incorporation, polymerization mechanisms and conditions, reactor configurations, special properties, rheological and processing behaviour, comparison with conventional polyolefins and fields of application. An essential book for plastics engineers, polymer chemists, physicists, materials scientists and all those working in the plastics manufacturing and processing industries.

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NATURE OF METALLOCENE CATALYSTS.
Metallocene Polymerization Catalysts: Past, Present and Future (J.Ewen).
Alkylalumoxanes: Synthesis, Structure and Reactivity (A. Barron).
MAO-free Metallocene Catalysts for Ethylene (Co)Polymerization (L.Resconi, et al.).
Influence of Metallocene Structures on Molecular andSupermolecular Architectures of Polyolefins (D. Fischer, et al.).
Olefin Polymerization by Monocyclopentadienyl Compounds ofTitanium, Zirconium and Hafnium (S. Ewart M. Baird).
Molecular Architecture: A New Application Design Process MadePossible by Single-site Catalysts (A. Torres, et al.).
Generation of Cationic Active Species for Olefin Polymerizationfrom ansa-Metallocene Amide Complexes (I. Kim).
Supported Metallocene Polymerization Catalysis (J. Chien).
Supported Metallocene Catalysts for Olefin Polymerization (G.Hlatky).
Homogeneous Phosphametallocene-based Catalysts for OlefinPolymerization (M. Sone).
Nickel- and Palladium-based Catalysts for the InsertionPolymerization of Olefins (L. Johnson C. Killian).
ETHYLENE POLYMERIZATION.
Structure, Properties and Preparation of Polyolefins Produced bySingle-site Catalyst Technology (P. Chum, et al.).
New Developments in the Production of Metallocene LLDPE byHigh-pressure Polymerization (A. Akimoto A. Yano).
Metallocenes as Catalysts for the Copolymerization of Ethene withPropene and Oienes (M. Galimberti, et al.).
Copolymerization of Ethylene with Dienes Using Metallocene/MAOCatalysts (G. Jiang).
Ethylene Polymerization Using a Metallocene Catalyst Anchored onSilica with a Spacer (D.-H. Lee S. Noh).
PROPYLENE POLYMERIZATION.
Synthesis of Isotactic Polypropylene by Metallocene and RelatedCatalysts (K. Soga, et al.).
Synthesis and Properties of Metallocene Catalysts for IsotacticPolypropylene Production (W. Spaleck).
Properties of Metallocene-catalyzed Isotactic Polypropylene (W.Spaleck).
Metallocene-catalyzed Syndiotactic Polypropylene: Preparation andProperties (T. Shiomura, et al.).
Synthesis of Atactic Polypropylene Using Metallocene Catalysts (L.Resconi).
Design of Ethylene-bridged ansa-Zirconocene Dichlorides for aControlled Propene Polymerization Reaction (J. Voegele, et al.).
Index.