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Azolides in Organic Synthesis and Biochemistry

Azolides in Organic Synthesis and Biochemistry

Heinz A. Staab, H. H. Bauer, K. M. Schneider

ISBN: 978-3-527-60083-0 August 2003 320 Pages

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Description

In the late fifties and early sixties H. A. Staab discovered N,N'-carbonyl-diimidazole (CDI), its analogues, and the family of azolides derived from them. Soon these compounds became widely appreciated as synthetic building blocks of unsurpassed diversity. The spectrum of substances, that can be obtained via mild acylation with azolides includes esters, amides, ketones, aldehydes, as well as heterocycles, peptides, glycosides, and nucleotides.

Now, H. A. Staab, the 'father' of these useful compounds, together with his coauthors H. Bauer and K. M. Schneider, has gathered their preparation, properties, and manifold applications in a comprehensive and topical overview.

Are you in the field of synthesis of natural products, biomolecules, heterocycles, or other complicated organic compounds? Then, your first glance might well be into 'Staab'- this handbook should always be within reach of your desk or lab bench.
Reactivity of Azolides
Preparation and Properties of Azolides
Syntheses of Carboxylic and Carbonic Esters
Syntheses of Amides and Analogous Compounds with NH-CO-Functions
Syntheses of Peptides
Modification and Immobilization of Proteins (Enzymes)
Syntheses of Heterocycles
Syntheses of Isocyanates, Isothiocyanates, Aminoisocyanates, Aminoisothiocyanates and N-Sulfinylamines
Reactions of Imino Analogues of Azolides
Syntheses of Sulfonates, Sulfinates, Sulfonamides, Sulfoxylates, Sulfones, Sulfoxides, Sulfites, Sulfates and Sulfanes
Reaction of Phosphines with N, N'-Carbonyldiimidazole (CDI)
Phosphorylation and Syntheses of Nucleotides
Syntheses of Acid Anhydrides and Acyl Chlorides
C-Acylations and other Element-Acylations
Syntheses of Aldehydes
Deoxygenation of Alcohols and C-C Coupling Reactions
Syntheses of Glycosides and Ethers
Intramolecular Dehydration
The Acyl Groups of Azolides as Protecting Groups
Azole Transfer
Syntheses of Halogenides/Pseudohalogenides and Aromatic Amines
Reactions with Vinylogous Azolides
Photochemical Reactions
Special Practical Applications and Analytical Methods