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Chemical Dynamics at Low Temperatures

Chemical Dynamics at Low Temperatures

Victor A. Benderskii, Dmitrii E. Makarov, Charles A. Wight

ISBN: 978-0-470-14147-2 December 2006 384 Pages

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Description

The first unified treatment of experimental and theoreticaladvances in low-temperature chemistry Chemical Dynamics at LowTemperatures is a landmark publication. For the first time, thecumulative results of twenty years of experimental and theoreticalresearch into low-temperature chemistry have been collected andpresented in a unified treatment. The result is a text/referencethat both offers an overview of the subject and contains sufficientdetail to guide practicing researchers toward fertile ground forfuture research. Topics covered include:
* Developmental history
* Formulation of general problems and the main approximations usedto solve them
* Specific features of tunneling chemical dynamics
* One-dimensional tunneling in the path integral formalism
* Special problems of two- and multidimensional tunneling
* An extended presentation of pertinent experimental results
From Thermal Activation to Tunneling.

One-Dimensional Models.

Two-Dimensional Tunneling.

Chemical Dynamics in the Presence of a Heat Bath.

Hydrogen Transfer.

Tunneling Rotation.

Vibration--Rotation Tunneling Spectroscopy of Molecules andDimers.

Heavy Particle Transfer.

Conclusion.

References.

Indexes.