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Chiral Auxiliaries in Cycloadditions

Chiral Auxiliaries in Cycloadditions

Karola Rück-Braun, Horst Kunz

ISBN: 978-3-527-61401-1

Sep 2008

186 pages

Select type: E-Book

$132.99

Description

Since the days of Diels, Alder and Woodward, cycloadditions have been among the most versatile reactions for stereoselective synthesis ...

All relevant information is collected in this well-structured, practical handbook. Arranged according to the cycloaddition type, the suitable auxiliaries, reactants, stereoselectivities, yields, and references for each key reaction are compiled in compact tables. Scientists interested in the theoretical background of stereoselective cycloadditions will find an excellent selection of in-depth literature references.

... with this comprehensive data collection cycloadditions will become an even more powerful tool for every organic chemist working on stereoselective synthesis.
[2+1] CYCLOADDITIONS (CYCLOPROPANATIONS)
Simmons-Smith Reactions
Cyclopropanations with Carbene Equivalents
Cyclopropanations with Ylide Reagents
Transition Metal Catalyzed Reactions of diazo Compounds
[2+2] CYCLOADDITIONS
Reactions of Imines with Ketenes (Staudinger Reactions)
Reactions of Keteniminium Salts with Alkenes
Reactions of Ketenes with Electronrich Alkenes
Reactions of Isocyanates with Alkenes
Photochemically Induced [2+2] Cycloadditions
[2+4] CYCLOADDITIONS (DIEL-ALDER REACTIONS)
Thermal Reactions
Lewis-acid Catalyzed Reactions
Intramolecular [4+2] Cycloadditions
HETERO [4+2] CYCLOADDITIONS
Reactions of Hetero-Dienophiles with Dienes
Reactions of Hetero-Dienes with Dienophiles
Intramolecular Hetero [4+2] Cycloadditions
[3+2] CYCLOADDITIONS (1,3-DIPOLAR CYCLOADDITIONS)
Chiral Dipolarophiles
Chiral Dipolars
CHIRAL AUXILIARIES
Alcohols
Amines
Amino Alcohols
Carboxylic Acids
Diols
Ketones
Oxazolidinones
Sultams
Sulfonic Acids
Miscellaneous Section