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Inorganic Syntheses, Volume 12

Inorganic Syntheses, Volume 12

Robert W. Parry (Editor-in-Chief)

ISBN: 978-0-470-13278-4

Sep 2009

344 pages

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Description

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.
Preface.

Notice to Contributors.

CHAPTER ONE METAL COMPLEXES OF MOLECULAR NITROGEN AND RELATED SPECIES.

1 Pentaammine(nitrogen)ruthenium(II) Salts and Other Ammines of Ruthenium.

2 trans-Chloro(nitrogen)-bis(triphenylphosphine)iridium(I).

3 trans-Hydrido(nitrogen)-tris(phenylphosphine)cobalt(I).

4 Trihydrido-tris(triphenylphosphine)cobalt(III) and Hydrido(nitrogen)-tris(triphenylphosphine)cobalt(I).

5 Azido(nitrogen)-bis(ethylenediamine)ruthenium(II) Hexafluorophosphate.

6 Azo, Diimide, and Hydrazine Complexes of Platinum.

CHAPTER TWO ORGANOMETALLIC COMPOUNDS.

I General Organometallics.

7 Substituted Iron Dicarbonyl Cations.

8 Tris(hydridomanganese Tetracarbonyl).

9 Organotin Hydrides.

10 Tetramethylgermane.

11 Organometallic Metal-Metal Bonded Derivatives.

12 Dimethylgallium(III) Hydroxide.

II Metal β-Keto-enolate Syntheses.

13 Tris(1,1,1,2,2,3,3-heptafluoro-7,7-dimethyl-4,6-octanedionato)iron(III) and Related Compounds.

14 Tetrakis(2,4-pentanedionato)cerium(IV) and Tetrakis(1,1,1-trifluoro2,4-pentanedionato)cerium(IV).

15 Tetracarbonyl(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)manganese(I).

16 Tris(3-cyanomethyl-2,4-pentanedionato)chromium(III).

17 Halo(2,4-pentanedionato)zirconium(IV) Complexes.

CHAPTER THREE SOME SIGNIFICANT COMPOUNDS OF BORON.

I Poly(1-pyrazolyl)borates and Their Complexes, Borane Adducts of Bases, and Haloborane Adducts of Bases.

18 Poly(1-pyrazolyl)borates, Their Transitional Complexes, and Pyrazaboles.

19 Borane Addition Compounds of Bases.

20 Trimethylamine-haloboranes.

II Compounds Containing Complex Boron Cations.

21 Cationic Bis(2,4-pentanedionato)boron(III) Complexes.

22 (4-Methylpyridine)(trimethylamine)dihydroboron(III) Cation Salts.

23 Bis(trimethylphosphine)dihydroboron(III) Iodide.

24 Tris(pyridine)hydroboron(III) Cation Salts.

25 Tetrakis(4-methylpyridine)boron(III) Cation Salts.

CHAPTER FOUR SOME SIGNIFICANT SOLIDS.

I Elemental Boron, Tungsten Bronzes, and Metal Sulfides.

26 Alpha-rhombohedral Boron.

27 Sodium Tungsten Bronzes.

28 Group IV Sulfides.

II Preparation of Some Metal Halides—Oxide Halides.

29 Molybdenum(II) Halides.

30 Molybdenum(III) Chloride.

31 Molybdenum(IV) Chloride.

32 Anhydrous Metal Halides, NbBr5, TaBr5, WCl6, MoCl5.

33 Molybdenum Oxide Trichloride.

34 Nonachlorotrihenium(III).

CHAPTER FIVE METAL COORDINATION COMPOUNDS.

35 Binuclear Complexes of Cobalt(III).

36 Pentammineperrhenatocobalt(III) Salts.

37 Linkage Isomers of Metal Complexes.

38 Hexahalogeno Salts and Alkyl Nitrile Complexes of Titanium(IV), Zirconium(IV), Niobium(V), Tantalum(V), Protactinium(IV) and -(V), Thorium(IV), and Uranium(IV).

39 Potassium Trichlorotrifluoroplatinate(IV) and Potassium Hexafluoroplatinate(IV).

40 Tetrakis(triphenylphosphine)dichlororuthenium(II) and Tris(triphenylphosphine)dichlororuthenium(II).

41 Di-μ-chloro-1,3-dichloro-2,4-bis(cyclohexyldiphenylphosphine)diplatinum(II) and Related Compounds.

42 Pentaammineiridium(III) Complexes.

43 Dicyanobis(1,10-phenanthroline)iron(II) and Dicyano-bis(2,2'-bipyridine)iron(II).

44 Diisothiocyanatotetrapyridine and Diisothiocyanatotetrapyridine Complexes of Dipositive First-transition-metal Ions (Manganese, Iron, Cobalt, Nickel, Copper, and Zinc).

45 α, β, γ, δ-Tetra(4-pyridyl)porphinezinc.

46 Poly{di-μ-(diphenylphosphinato)}aquohydroxychromium(III).

47 Dihalogenodinitrosylmolybdenum and Dihalogenodinitrosyltungsten.

48 Sodium (+)-Arsenyl Tartrate.

49 Resolution of Tris(ethylenediamine)rhodium(III) and -chromium(III) Chloride by Means of (+)-Tartrate..

CHAPTER SIX NONMETAL SYSTEMS.

I Phosphorus Compounds.

50 Difluorophosphines.

51 Dimethylthiophosphinic Bromide.

52 (Trichloromethyl)dichlorophosphine.

53 Phenyl-substituted Phosphonitrile Fluoride Trimers.

II Fluorine Compounds.

54 Difluoroamido Compounds–Extra-hazardous Materials.

55 1,1-difluorourea Solutions and Difluoroamine–Extra-hazardous Materials.

56 Bis(trifluoromethyl) Trioxide–Hazardous Materials.

Appendix.

Index of Contributors.

Subject Index.

Formula Index.