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Inorganic Syntheses, Volume 13



Inorganic Syntheses, Volume 13

F. Albert Cotton (Editor-in-Chief)

ISBN: 978-0-470-13279-1 September 2009 267 Pages

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The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.

Notice to Contributors.

Chapter One Compounds of the Nontransition Elements.

1 Perbromic Acid and Potassium Prebromate.

2 α-Sulfanuric Chloride—Cyclic Trimer.

3 Arsine and Arsine-d3.

4 Ammonium Cyanate.

5 Phosphorus(III) Isocyanate.

6 Phosphoramidic Acid and Its Salts.

7 Diphenyl(trimethylsilyl)phosphine and Dimethyl(trimethylsilyl)phosphine.

8 Exchange Reactions for the Syntheses of Phenylboron Chlorides and Tetrafluoromethylphosphorane.

9 2,4,6-Trichloroborazine.

10 2,4,6-Trichloro-1,3,5-trimethylborazine.

Chapter Two Organometallic Compounds.

11 Cyclic-diolefin Complexes of Platinum and Palladium.

12 Cationic Diene Complexes of Palladium(II) and Platinum(II).

13 Trichloro-, Trimethyl-, and Trifluorosilylcobalt Tetracarbonyl.

14 Isoleptic Allyl Derivatives of Various Metals.

Chapter Three Compounds Containing Metal-to-Metal Bonds.

15 Rhenium and Molybdenum Compounds Containing Quadruple Bonds.

16 Tetrakis(acetato)dirhodium(II) and Similar Carboxylato Compounds.

17 Dodecacarbonyltriruthenium and -triosmium.

18 Dodecacarbonyltetrairidium.

19 Disodium Hexaalkoxy-octa-μ3-chloro-hexamolybdates.

Chapter Four Phosphine and Phosphite Complexes of Low-Valent Metals.

20 Triaryl Phosphite Complexes of Cobalt, Nickel, Platinum, and Rhodium.

21 Tetrakis(triethyl phosphite)nickel(0), Palladium (0), and Platinum(0) Complexes.

22 Low-valent Metal Complexes of Diethyl Phenylphosphonite.

23 Tetrakis(triphenylphosphine)palladium(0).

24 Tetrakis(triphenylphosphine)nickel(0).

25 Carbonylhydridotris(triphenylphosphine)iridium(I).

26 Chlorohydridotris(triphenylphosphine)ruthenium(II).

Chapter Five Binary Compounds of the Transistion Metals.

27 Single Crystals of Transition-metal Dioxides.

28 Molybdenum(V) Fluoride.

29 Tungsten(V) Chloride.

30 Anhydrous Nickel(II) Halides and Their Tetrakis(ethanol) and 1,2-dimethoxyethane Complexes.

Chapter Six Halo Complexes of Some Metals.

31 Tetraphenylarsonium Tetrachlorovanadate(III).

32 Tris(tetraethylammonium) Nonachlorodivanadate(III).

33 Ammonium, Rubidium, and Cesium Salts of the Aquapentachloromolybdate(III) and Hexachloromolybdate(III) Anions.

34 Disodium Hexachloropatinate(IV).

Chapter Seven Various Transition-Metal Compounds.

35 Dichlorotetrakis(2-propanol)vanadium(III) Chloride.

36 Trichorobis(trimethylamine)vanadium(III).

37 Vanadyl(IV) Acetate, VO(CH3CO2)2.

38 Tris(diamine)chromium(III) Salts.

39 Bis[cis-1,2-dicyanoethene-1,2-dithialato(1 or 2–)] Complexes of Cobalt and Iron.

40 Resolution of the (Ethylenediamine)bis(oxalato)cobaltate(III) Ion.

41 Nitrito Complexes of Nickel(II) and Cobalt(II).

42 Ruthenium Ammines.

43 Pentaamminechlororhodium(III) Dichloride and Pentaamminehydridorhodium(III) Sulfate.

44 Dichloro(ethylenediamine)palladium(II) and (2,2'-Bipyridine)dichloropalladium(II).

45 Nonahydridorhenate Salts.

46 Potassium Hexakis(isothiocyanato)niobate(V).


Index of Contributors.

Subject Index.

Formula Index.