Skip to main content

Inorganic Syntheses, Volume 20

Inorganic Syntheses, Volume 20

Daryle H. Busch (Editor-in-Chief)

ISBN: 978-0-470-13286-9

Sep 2009

303 pages

Select type: E-Book

$39.99

Description

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.
Chapter One SOLID STATE.

1. Crystal Growth in Gels.

2. Crystal Growth in Gels.

3. Single-Crystal Growth by a Double-Infusion Technique.

4. Crystalline Silver Chloride.

5. The Partially Oxidized Platinum Complex Rubidium Tetracyanoplatinate [Hydrogen Bis(sulfate)] (3:1:0.46): Rb3[Pt(CN)4](SO4-H-O4S)0,46-H2O.

6. The Rubidium-Cesium Partially Oxidized Tetracyanoplatinate (Hydrogen Difluoride)-Fluoride Systems.

Chapter Two STOICHIOMETRICALLY SIMPLE COMPOUNDS.

7. Tellurium Tetrafluoride.

8. Sulfur Tetrafluoride Oxide.

9. Selenonyl Difluoride.

10. Hydrogen Pentafluorooxoselenate(VI).

11. Rhenium Pentachloride and Volatile Metal Chlorides by Direct Chlorination Using a Vertical-Tube Reactor.

12. Trirhenium Nonachloride.

13. Trirhenium Nonahalides.

14. β-Platinum(I1) Chloride.

15. Divalent Metal Chromium(II1) Oxides (Chromites).

16. Copper(1) Acetate.

Chapter Three COORDINATION COMPOUNDS.

17. Compounds Containing the cis-Bis(ethylenediamine)rhodium(III) Species.

18. Potassium Tetrahydroxodioxoosmate(V1) and trans- Bis(ethy1enediamine) dioxoosmium(V1) Chloride.

19. Sodium Bis[2-ethyl-2-hydroxybutyrato(2-)] oxochromate(V).

20. The Bis(b-diketonato)platinum(II) Complexes.

21. Trimethylphosphine Iron Complexes.

22. Pentakis(trimethy1 phosphite)complexes of the d8 transition metals.

23. Complexes of Aluminum Iodide with Pyridine and Related Bases.

Chapter Four COMPLEXES WITH COMPLICATED CHELATE LICANDS.

24. Caged Metal Ions: Cobalt Sepulchrates.

25. Clathrochelates Formed by the Reaction of Tris(2,3-butanedione Dihydrazone)metal Complexes with Formaldehyde: [5,6,14,15,20,21- Hexamethyl-1,3,4,7,8,10,12,13,16,17,19,22dodecaazatetracyclo- [8.8.413,17-18,12] tetracosa-4,6,13,15,19,12-hexaene- N4, N7, N13 , N16 ,N19, N22] metal(n+) Tetrafluoroborate.

26. Compartmental Ligands.

27. [7,12: 21,26-Diimino-l9,14;28,33:35,5-trinitrilo-5Hpentabenzo [c,h,m,r,w] [1,6,11,16,21] pentaazacyclopenta-cosinato(2-)]-dioxouranium(VI) (Uranyl Superphthalocyanine).

Chapter Five COMPOUNDS OF BIOLOGICAL INTEREST.

28. Metallointercalation Reagents: Thiolato Complexes of (2,2': 6',2"- terpyridine)platinum(II).

29. Saturated, Unsubstituted Tetraazamacrocyclic Ligands and Their Cobalt(II1) Complexes.

30. [7,16-Dihydro-6 ,8,15,17-tetramethyldibenzo[b,i] [1,4,8,11]-tetraazacyclotetradecinato(2-)] nickel(II), ([5,7,12,14-Me4-2,3:9,10-Bzo2-[14] hexaenato(2-)N4] Ni(II) and the Neutral Macrocyclic Ligand.

31. The Synthesis of Molybdenum and Tungsten Dinitrogen Complexes.

32. Bis[2,3-butanedione dioximato(1-)] cobalt Complexes.

33. Cobalamins and Cobinamides.

34. Metalloporphines.

35. Iron Porphines.

36. Metallophthalocyanins and Benzoporphines.

37. (Dioxygen)(N-methylimidazole)[(all-cis)-5,10,15,20-tetrakis [2-(2, 2-dimethylpropionamido)phenyl] porphyrinato(2-)-iron(II).

Chapter Six ORGANOMETALLIC COMPOUNDS.

38. Silyl and Germyl Selenides and Tellurides.

39. Digermoxane and 1,3-Dimethyl-, 1,1,3,3-Tetramethyl-, and Hexamethyldigermoxane.

40. Di-μ-chloro-dichlorobis (ethylene) diplatinum(II), Di-μ-chlorodichlorobis(styrene) diplatinum (II), and Di-μ-chloro-dichlorobis- (1-dodecene)diplatinum(II).

41. Dibromomethylplatinum(IV) and Dihydroxodimethylplatinum(IV) Sesquihydrate.

42. Halocyclopentadienyl Complexes of Manganese and Rhodium.

43. (η6-Benzene)(η5-cyclopentadienyl)molybdenum and (η6-Benzene)- (η5-cyclopentadienyl)molybdenum Derivatives.

44. cis-[Acetyltetracarbonyl(l -hydroxyethylidene) rhenium] (cis-Diacetyltetracarbonylrhenium hydrogen).

45. cis- [Acetyl(1-aminoethylidene)tetracarbonylrhenium] - [cis-(Acetimidoyl)(acetyl)tetracarbonylrhenium hydrogen)].

46. Hydrido Complexes of Cobalt with Bis(phosphines).

Chapter Seven METAL CLUSTER COMPLEXES.

47. Tri-μ-carbonyl-nonacarbonyltetrarhodium, Rh4(CO)9(μ-CO)3.

48. Disodium μ6-Carbido-nona-μ-carbonyl-hexacarbonylhexarhodate- (2-),K2[Rh6(CO)6(μ-CO)95-C)].

49. Disodium Di-μ-carbonyl-octa-μ3-carbonyl-icosacarbonyldodecarhodate (2-), Na2 [Rh12(CO)20(μ-CO)23-CO)8].

50. μ-Nitrido bis(triphenylphosphorus(1+) Undecacarbonyl- hydridotriferrate(1-), [(Ph3P)2N] [Fe3H(CO)11].

51. Bis[μ-nitrido-bis(tripheny1phosphorus)(1+)] Undecacarbonyltriferrate, [(Ph3P)2N]2 [Fe3(CO)11].

52. μ3-Alkylidyne-tris(tricarbonylcoba1t) Compounds: Organocobalt Cluster Complexes.

53. μ3-Methylidyne- and μ3-Benzylidyne-tris(tricarbonylcoba1t).

54. μ3 [(Ethoxycarbonyl)methylidyne]- and μ3-{[(Methylamino)- carbonyl] methylidyne} -tris(tricarbonylcobalt).

55. μ3-(Chloromethylidyne)-and μ3-[ tert-butoxycarbony1)- methylidyne] -tris(tricarbonylcobalt).

56. Tetracarbonyl bis-μ-(2-methyl-2-propane thiolato)diiridium(I).

57. Decacarbonyl-μ-[diborane(6)]-μ-hydrido-trimanganese.

Correction.

Index of Contributors.

Subject Index.

Formula Index.