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Inorganic Syntheses, Volume 21

Inorganic Syntheses, Volume 21

John P. Fackler Jr. (Editor-in-Chief)

ISBN: 978-0-470-13252-4

Jan 2007

215 pages

Select type: O-Book

Description

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.
Chapter One METAL CHALCOGENIDE COMPOUNDS.

1. Synthesis of (η6-Benzene) dicarbonyl (selenocarbonyl) chromium(0) and Pentacarbonyl (selenocarbonyl) chromium(0).

2. Diselenocarbamates from Carbon Diselenide.

3. Polysulfide Chelates.

4. Di-μ-chloro-Tetrachloro-μ -(dimethyl sulfide) -bis(dimethyl sulfide)diniobium(III).

5. (2-Aminoethanethiolato-N,S,) bis(1,2-ethanedamine)cobalt(III), (2-Mercaptoacetato-O,S) bis(1,2-ethanediamine) cobalt(III), and Related Complexes.

6. Tetrakis (benzenethiolato) metallate(2-) complexes, [M(SPh)4]2-, of Manganese, 1ron,Cobalt, Zinc, and Cadmium and Derivatives of the [Fe(SPh)4]2- Complex.

7. Tri-μ-chloro-chlorotetrakis(triphenylphosphine) diruthenium(II) Complexes with Acetone Carbonyl and Thiocarbonyl Ligands.

8. (L-Cysteinato)gold(I).

9. Tetranuclear Iron-Sulfur and IronSelenium Clusters.

10. Polynuclear Cyclopentadienyliron Complexes Containing the S2 Ligand.

Chapter Two DINUCLEAR AND POLYNUCLEAR COMPOUNDS.

11. Binuclear Transition Metal Complexes Bridged by Methylene bis(diphenylphosphine).

12. Synthesis of Dimethylamido Compounds Containing Metal-to-Metal Triple Bonds Between Molybdenum and Tungsten Atoms.

13. Tetranuclear Mixed-Metal Clusters.

14. Bis [μ-nitrido-bis [triphenylphosphonis(1+)] Tridecacarbonyltetraferrate (2-) or [bis(triphenylphosphine) irninium tridecacarbonyltetraferrate] (2-)[PPN]2[Fe4(CO)13].

Chapter Three ORGANOMETALLIC COMPOUNDS.

15. Chlorobis (pentafluorophenyl) thallium(III).

16. (η6-Hexamethylbenzene) ruthenium Complexes.

17. Some η5-Cyclopentadienylruthenium(II) Complexes Containing Triphenylphosphine.

18. Cyclopentadienyl Complexes of Titanium(III) and Vanadium(III).

19. Dichloro(ethene) (N,N,N',N'-tetraethyl -1,2-ethanediamine).

20. 1,2-Ethanediylbis (diphenylphosphine) Complexes of Iron.

Chapter Four COORDINATION COMPOUNDS.

21. trans-Carbonylchlorobis (dimethylphenylphosphine) iridium(I).

22. Carbon Dioxide Complexes of Rhodium and Iridium.

23. Tris (acetonitrile)nitrosylbis (triphenylphosphine) iridium(III) bis[hexafluorophosphate].

24. Stable Copper(I) Carbonyl Complexes.

25. {[Tris{μ-[(1,2-cyclohexanedione dioximato)-0:0']} diphenyldiborato (2-)] -N,N',N"",N'"",N"""",N'""""} iron(II).

26. Ternary Complexes of Copper(II).

27. Preparations of trans-Dioxotetrakis (pyridine)rhenium(V) Chloride, [ReO2py4] Cl, and Perchlorate, [ReO2py4] ClO4.

28. Dibromo-, Aquabromo-, and Aquachlorobis(1,2-ethanediamine) cobalt(III) Complexes.

29. Tris(2,2'-bipyridine) ruthenium(II) dichloride Hexahydrate.

30. Alkylated Polyamine Complexes of Palladium(II).

31. Tetrahydrofuran Complexes of Selected Early Transition Metals.

Chapter Five SOLID STATE.

32. One-Dimensional Tetracyanoplatinate Complexes Containing Platinum-Atom Chains.

Chapter Six STOICHIOMETRICALLY UNCOMPLICATED COMPOUNDS.

33. Tetraammonium Diphosphate.

34. Tetrabutylammonium Tetrachlorooxotechnetate(V).

35. Uranium(V) Fluorides and Alkoxides.

36. Sodium Cyanotri[(2H)hydro] borate(1-).

37. Potassium Pentafluorooxomolybdate(V).

38. Cyclooctasulhr Monoxide.

Chapter Seven LIGANDS AND REAGENTS.

39. Substituted Triaryl Phosphines.

40. Dimethylphosphine.

41. 1,2,3,4,5-Pentamethylcyclopentadiene.

42. Vanadium Dichloride Solution.

43. Uranium(IV) Chloride for Organometallic Synthesis.

CORRECTION.

Preparation of [Pt(H2O)4]2+ Stock Solution.

Index of Contributors.

Subject Index.

Formula Index.