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Inorganic Syntheses, Volume 25

Inorganic Syntheses, Volume 25

Harry R. Allcock (Editor-in-Chief)

ISBN: 978-0-471-61874-4

Feb 1989

300 pages

Out of stock

$210.00

Description

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.
Chapter One MAIN GROUP RING SYSTEMS AND RELATED COMPOUNDS.

1. Organocyclophosphanes.

2. Diethylammonium cyclo-Octathiotetraphosphate(III).

3. Tervalent Phosphorus-Nitrogen Ring Compounds.

4. 2,4,6-Trichloro-1,3,5-triethylcyclophosph(III)azanes- (1,3,5,2,4,6-Triazatriphosphorinanes).

5. Aminocyclotetraphosphazenes and Transannular Bridged Bicyclic Phosphazenes.

6. Chlorofunctional 1, 3, 5, 2λ5, 4λ5-Triazadiphosphinines.

7. Binary Cyclic Nitrogen-Sulfur Anions.

8. Binary Catena-Nitrogen-Sulfur Anions.

9. Pentanitrogen Tetrasulfide Chloride, (N5S4)Cl [1λ4, 3λ4, 5λ4, 7-Tetrathia-2, 4, 6, 8, 9-pentaazabicyclo [3.3.l] nona-l(8), 2, 3, 5- tetraenylium Chloride].

10. (N3P2S)ClPh4, 1-Chloro-3, 3, 5, 5-tetraphenyl -lλ4, 2, 4, 6, 3λ5, 5λ5 -thiatriazadiphosphorine.

11. Silicon and Tin Sulfur-Nitrogen Compounds, (Me3Si)2N2S, (Me3Sn)2N2S, and (Me2Sn)S2N2.

12. 1, 1, l-Trimethyl-N-sulfinylsilanamine, Me3SiNSO.

13. Sulfur-Nitrogen Rings Containing Exocyclic Oxygen.

Chapter Two INORGANIC POLYMER SYSTEMS.

14. Organosilane High Polymers: Poly(methylphenylsily1ene).

15. Organosilicon Derivatives of Cyclic and High Polymeric Phosphazenes.

16. Poly (dimethylphosphazene) and Poly (methylphenylphosphazene) {Poly [nitrilo (dimethylphosphoronylidyne)] and Poly [nitrilo (methylphenylphosphoranylidyne)]}.

17. Pentachloro (vinyloxy) cyclotriphosphazenes and Their Polymers [2, 2, 4, 4, 6-Pentachloro-6-(ethenyloxy)-1, 3, 5, 2λ5, 4λ5, 6λ5-triazatriphosphorin.

Chapter Three COMPOUNDS OF PHARMACOLOGICAL INTEREST.

18. Boron Analogs of Amino Acids.

19. 1-Aziridinyl-Amino Substituted Cyclophosphazenes.

20. cis-Diammineplatinum α-Pyridone Blue.

Chapter Four METAL COMPOUNDS, COMPLEXES, AND LIGANDS.

21. Dipotassium Tetraiodoplatinate(II) Dihydrate.

22. Alkyl or Aryl Bis(tertiary phosphine) Hydroxo Complexes of Platinum(II).

23. Tris(bidentate)ruthenium(II) Bis(hexafluoroph0sphate) Complexes.

24. Potassium Trialkyl- and Triarylstannates: Preparation by the Deprotonation of Stannanes with Potassium Hydride.

25. (Benzenethio1ato)tributyltin.

26. Use of (Benzenethiolato)tributyltin to Prepare Complexes of Manganese Carbonyl Having Bridging Thiolate Ligands.

27. Methylenebis [dichlorophosphine] (Methylenebis[phosphorous Dichloride]), Chlorobis [(dichlorophosphino) methyl] phosphine ([Chlorophosphindenebis (meth ylene)] bis[phosphorous Dichloride]), and Methylenebis [dimethylphosphine].

28. 1,4,7,10,13,16- Hexathiacyclooctadecane (Hexathia-18-crown-6 and Related Crown Thioethers).

29. ([18]Crown-6)Potassium Dicyanophosphide(1-).

30. (2-Diphenylphosphino) benzenamine.

31. Sodium Salt of (1R)-3-Nitrobornan-2-one (Sodium d-α-camphornitronate).

32. Tris(glycinato)cobalt(III).

33. Resolution of the Tris(oxalato)chromate(III) Ion by a Second-Order Asymmetric Synthesis.

34. Difluorodioxouranium(VI).

35. The Ammonium Chloride Route to Anhydrous Rare Earth Chlorides--The Example of YCl3.

Chapter Five TRANSITION METAL ORGANOMETALLIC COMPOUNDS.

36. Bis(phosphine) Derivatives of Iron Pentacarbonyl and Tetracarbonyl(tri-tert-butylphosphine)iron(0).

37. Tricarbonyl Bis(N,N-dialkycarbamodithiolate) tungsten(II).

38. Cyclopentadienylbis(trimethylphosphine) and Cyclopentadienylbis (trimethylphosphite) Complexes of Co and Rh.

39. Mixed Cobalt-Ruthenium Dodecacarbonyl Clusters: Dodecacarbonylhydridotricobaltruthenium, Co3RuH(CO)12.

40. Dinuclear Phosphido and Arsenido Derivatives of Molybdenum.

41. Dicarbonylbis(di-tert-butylphosphine)(μ-di-tert-butylphosphido)- μ-hydrido-dirhodium(1+) (Rh2(μ-t-Bu2P)-(μ-H) (CO)2(t-Bu2PH)2 and μ-Chloro-bis (η4-1,5-cycloocta- diene)( μ-di-tert-butylphosphido) dirhodium(1+) (Rh2(μ-t-Bu2P) μ-Cl(cod)2, cod = 1,5-cyclooctadiene).

42. Bis-tert-butylphosphido (t-BuP(H)-) Bridged Dimers of Rhodium(1+) and Nickel(1+) Containing Rh=Rh Double and Ni-Ni Single Bonds.

43. Tetracarbonylbis (μ-di-tert-butylphosphido) dicobalt(I) [Co(μ-t-Bu2P)(CO)2]2.

44. (η5-Cyclopentadieny1)diruthenium Complexes.

45. Di-μ-iodo-bis( tricarbonylosmium), Bis (tetracarbonyliodoosmium), and Dicarbonyliodo- (η5-Cyclopentadieny1) osmium.

46. μ-Nitrido-bis(triphenylphosphorus (1+) μ-carbonyldecacarbonyl-μ-hydridotriosmate(1-).

47. Decarbonyl-(η5-cyclopentadienyl) dihydrocobalttriosmium, CoOs3(μ-H)25-C5H5) (μ-CO) (CO)9; Nonacarbonyl-(η5-cyclopentadieny1) trihydrido- and (η5-Cyclopentadienyl)- tetrahydridocobalttriosmium CoOs3(μ-H)45-C5H5) (CO)9 and CoOs3(μ-H)45-C5H5) (CO)9.

Index of Contributors.

Subject Index.

Formula Index.