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Inorganic Syntheses, Volume 27

Inorganic Syntheses, Volume 27

Alvin P. Ginsberg (Editor-in-Chief)

ISBN: 978-0-470-13258-6

Jan 2007

464 pages

Description

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.
Chapter One TRANSITION METAL POLYHYDRIDE COMPLEXES.

1. Molecular Hydrogen Complexes of Mo and W.

2. Molybdenum and Tungsten Phosphine Polyhydrides.

3. Heptahydridobis (triphenylphosphine) rhenium(VII) and Octahydridotetrakis (triphenylphosphine) dirhenium(IV).

4. Tetrahydrid (η5-pentamethylcyclopentadienyl) iridium.

5. Tris[1,3-bis(diphenylphosphino) propane]-heptahydridotriiridium(2 + ) Bis(tetrafluoroborate) and Bis[1,3-bis (diphenylphosphino) propane]-pentahydridodiiridium(1 + ) Tetrafluotoborate.

6. Heterobimetallic Hydride Complexes.

7. μ-Hydrido-tetrakis(tertiary phosphine) diplatinum Cations.

Chapter Two TRANSITION METAL CHALCOGENIDE COMPLEXES.

8. Tetraphenylphosphonium Salts of [Mo2(S)n(S2)6-n]2- Thioanions and Derivatives.

9. Molybdenum-Sulfur Clusters.

10. Bis(η5-methylcyclopentadienyl) titanium Pentasulfide, Bis(η5-methylcyclopentadienyl) divanadium Pentasulfide, and

Bis(η5-methylcyclopentadienyl) divanadium Tetrasulfide.

11. Cyclometallapolysulfanes (and Selanes) of Bis(η5-cyclopentadienyl) Titanium(IV), Zirconiurn(IV), Molybdenum(IV), and Tungsten(IV).

12. Bis(hydrogensulfido) Complexes of Bis(η5-cyclopentadienyl) Titanium(IV) and Tungsten(IV).

13. (μ-Disulfido-S) (μ-disulfido-η22) Bis(η5-pentamethyl- cyclooentadienyl) (μ-thio)dichromium (Cr-Cr).

Chapter Three EARLY TRANSITION METAL POLYOXOANIONS.

14. Introduction to Early Transition Metal Polyoxoanions.

15. Tetrabutylammoniurn Isopolyoxometalates.

16. α, β, and γ-Dodecatungstosilicic Acids: Isomers and Related Lacunary Compounds.

17. Vanadium(V) Substituted Dodecatungstophosphates.

18. Potassium Octadecatungstodiphosphates(V) and Related Lacunary Compounds.

19. The Aquatrihexacontaoxobis [trioxoarsenato(III)]- henicosatungstate(6-) Anion Isolated as the Acid or as the Rubidium Salt.

20. The Sodium Pentaphosphato(V) Triacontatungstate Anion Isolated as the Ammonium Salt.

21. Tetracontatungstotetraarsenate(III) and Its Cobalt(II) Complex.

22. Ammonium Sodium Henicosatungstononaantimonate(III), (NH4)18[NaSb9W21O86] 24H2O.

23. Bis(μ5-organophosphonato-O, O', O") -penta-μ-oxo-pentakis (dioxomolybdates, -tungstates) (4-) (Pentametallobisphosphonates).

24. Tetrakis(tetrabutylammonium) μ3-[η5-Cyclopentadienyl) -trioxotitanate(IV)] -A-β-1, 2, 3 -trivanadononatungstosilicate(4-), [(C4H9)4N]4 [A-β-(η5-C5H5) TiSiW9V3O40]. 

Chapter Four LANTHANIDE AND ACTINIDE COMPLEXES.

25. Lanthanide Trichlorides by Reaction of Lanthanide Metals with Mercury(II) Chloride in Tetrahydrofuran.

26. Bis(phenylethynyl)ytterbium(II) from Ytterbium Metal and Bis(phenylethyny1)mercury.

27. Bis[bis(trimethylsilyl)amido] bis(diethyl ether)ytterbium and (Diethyl ether) bis(η5-pentamethylcyclopentadienyl) ytterbium.

28. Cyclooctatetraene lanthanide Complexes: Lu(C8H8)Cl(thf) and Lu(C8H8) [o-C6H4CH2N(CH3)2](thf).

29. Bis(η5-pentamethylcyc1opentadienyl) bis(tetrahydrofuran)-samarium(II).

30. tert-Butylbis(η5-cyclopentadienyl) (tetrahydrofuran)-neodymium.

31. Bis(η5-cyclopentadienyl) (tetrahydrofuran)- [(trimethylsilyl)methyl] lutetium and Bis(η5-cyclopentadienyl)- (tetrahydrofuran)p-tolyllutetium.

32. Hydrocarbon-Soluble Homoleptic Bulky Aryl Oxides of the Lanthanide Metals: [Ln(OArR)3].

33. Bis[η5-1, 3-bis(trimethylsilyl)cyclopentadienyl]- chlorolanthanide(III) Complexes, [{ LnCp''2(μ-Cl)}2] and [LnCp"2(μ-Cl)2Li(thf)2].

34. Bis[η5-1, 3-bis(trimethylsilyl) cyclopentadienyl] halouranium(IV) and -Thorium(IV), [MCp"2Cl2] and [UCp"2X2].

35. Tris(η5-cyclopentadienyl) [(dimethylphenylphosphoranylidene)- methyl] uranium(IV).

Chapter Five TRANSITION METAL CLUSTER COMPLEXES.

36. Tetrairon Carbido Carbonyl Clusters.

37. Tetraethylammonium Dodecacarbonyltricobaltferrate(1 - ) and (Triphenylphosphine)gold (1 + ) Dodecacarbonyl- tricobaltferrate(1 -).

38. Chiral Trinuclear NiCoMo and MoRuCo clusters.

39 . Nonacarbonyl-tri-μ-hydrido-μ3-methylidyne-triruthenium and -osmium.

40. Anionic and Heteronuclear Triosmium Clusters.

41. Hexachlorododecakis (triphenylphosphine)- pentapentacontagold, Au55[P(C6H5)3]12Cl6.

42. A Platinum-Gold cluster: Chloro-1k Cl-bis(triethy1phosphine-1kP) bis(triphenylphosphine)-2kP, 3kP-triangulo- digoldplatinurn (1 + ) Trifluoromethanesulfonate.

Chapter Six PHOSPHORUS COMPLEXES AND COMPOUNDS.

43. Chloro(η2-tetrahedro-tetraphosphorus) bis(triphenyIphosphine)-rhodium(I).

44. Tetracarbonyl bis(η5-cyclopentadienyl) (μ-η2-diphosphorus)- dimolybdenum(I) and Dicarbonyl (η5-cyclopentadienyl)- (η3-cyclo- triphosphorus) molybdenum(I)

45. Trilithium Heptaphosphide, Dilithiun Hexadecaphosphide, and Trisodium Henicosaphosphide.

46. Phosphorus Compounds Containing Sterically Demanding Groups.

47. Compounds with Unsupported P=P Bonds.

48. Tris(trimethylsily) phosphine and Lithium Bis(trimethylsilyl) -phosphide.bis(tetrahydrofuran).

49. (2,2-Dimethylpropylidyne)phosphine.

50. Triphosphenium Salts.

51. cis-1, 3-Di-tert-butyl-2, 4-dichloro-3, 2, 4-diazadiphosphetidine.

Chapter Seven TRANSITION METAL COMPLEXES OF BIOLOGICAL INTEREST.

52. Reversible Cobalt(II) and Iron(II) Dioxygen Carriers of Totally Synthetic Lacunar Cyclidene Complexes.

53. [Pt(1, 2-Cyclohexanediamine) (ascorbato-C2, O5)].

Chapter Eight MISCELLANEOUS TRANSITION METAL COMPLEXES.

54. (Dithiocarbonato) [1, 1, l-tris(diphenylphosphinomethyl) ethane]-rhodium(III) Tetraphenylborate Solvate.

55. The Vaska-Type Rhodium Complexes, trans-RhX(CO)L2.

56. Potassium Hexaiodorhenate(IV).

57. Group 6 Pentacarbonyl Acetates as Their μ-Nitridobis(triphenylphosphorus)( 1 + ) Salts.

58. Bis(organoimido) Complexes of Tungsten(VI).

59. Relatively Air-Stable M(II) Saccharinates, M = V or Cr.

60. Pyridinium Fluorotrioxochromate(VI), (C5H5NH)[CrO3F].

61. Dipotassium Trifluorosulfatomanganate(III).

62. cis-Dichlorobis (1,2-ethanediamine) platinurn(IV) Chloride.

63. Bis(1, 1, 1, 5, 5, 5-hexafluoro-2,4-pentanedionato) palladium and Its Complexes with 2, 2'-Bipyridine and Bis[2-(diphenylphosphino)ethyl] phenylphosphine.

Chapter Nine LIGANDS AND OTHER MAIN GROUP COMPOUNDS.

64. Hybrid Tertiary Phosphine Amine and Amide Chelate Ligands: N-[2-(diphenylphosphino)phenyl] benzamide and 2-(Diphenylphosphino)-N-phenylbenzamide.

65. 1, 1-Dimethyl-N-(trimethy1silyl)ethanamine.

66. Ethynylpentafluoro-λ6-sulfane (SF5C triplebond CH).

67. Iodine and Bromine Polysulfur Hexafluoroarsenate(V) and Hexafluoroantimonate(V).

68. Trimethylborane.

Sources of Chemicals and Equipment.

Index of Contributors.

Subject Index.

Formula Index.