Skip to main content

Inorganic Syntheses, Volume 8

Inorganic Syntheses, Volume 8

Henry F. Holtzclaw Jr. (Editor-in-Chief)

ISBN: 978-0-470-13239-5

Jan 2007

319 pages

Select type: O-Book

Description

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.
Preface.

Notice to Contributors.

Chapter IA.

Alkali Metal Compounds.

Chapter IB.

1 Bis(4-imino-2-pentanonato)copper(II) and Bis(2-phenyl-imino-1-phenyl-1-butanonato)copper(II).

Chapter IIA.

2 Complex Carbonates of Beryllium.

Chapter IIB.

3 Dichloro(2,2'-iminodipyridine)zinc, Diacetato(2,2'-iminodipyridine)zinc, and Dicyano(2,2'-iminodipyridine)zinc.

Chapter IVA.

4 Sodium Bis(trimethylsilyl)amide and Tris(trimethylsilyl)amine.

5 Lithium Bis(trimethylsilyl)amide and Tris(trimethylsilyl)amine.

6 Silicon Tetraisocyanate and Methylsilicon Isocyanates.

7 Silicon Tetraisothiocyanate and Methylsilicon Isothiocyanates.

8 Tetraphyenylgermane and Hexaphenyldigermane.

9 Potassium Trioxalatogermanate(IV).

Chapter IVB.

10 Dichlorobis(2,4-pentanedionato)titanium(IV): (Correction).

11 Tris(2,4-pentanedionato)zirconium(IV) Chloride.

12 Potassium Tetraoxalatozirconate(IV), -hafnate(IV), and -thorate(IV).

Chapter VA.

13 Metal Derivatives of β-Keto Imines (β-Imino Ketones).

14 Ammonium Azide.

15 Phenyllead(IV) Azides.

16 Tetraphosphorus Hexamethylhexaimide.

17 Diphenyl Phosphorochloridite.

18 Diphenylphosphinic Acid.

19 (2,2-Dimethylhydrazino)diphenylphosphine.

20 Alkoxy- and Aryloxycyclophosphazenes.

21 Mercapto Derivatives of Chlorocyclophosphazenes.

22 (Trichlorophosphoranylidene)amidophosphoryl dichloride.

23 Trichloro[(trichlorophosphoranylidene)amino]phosphorus(V) hexachlorophosphate.

Chapter VIA.

24 Hexaatomic Sulfur.

25 Heptasulfur Imide.

26 Imidodisulfuric Acid Chloride.

27 Dialkylsulfamoyl Chlorides.

28 N- and N,N'-Substituted Sulfamides.

29 Dialkylamides of (Trichlorophosphoranylidene)sulfamic Acid.

30 Bis(trichlorophosphoranylidene)sulfamide.

31 Aminomethanesulfonic Acid.

Chapter VIB.

32 Anhydrous Chromium(II) Acetate, Chromium(II) Acetate 1-Hydrate, and Bis(2,4-pentanedionato)chromium(II).

33 Diperoxotriamminechromium(V).

34 Tris(1,3-diphenyl-1,3-propanedionato)chromium(III).

35 Tris(1,1,1-trifluoro-2,4-pentanedionato)chromium(III).

36 Tris(1,3-propanedialato)chromium(III).

37 cis- and trans-Tris(3-oxobutanalato)chromium(III).

38 Tris(4-p-toluidino-3-penten-2-onato)chromium(III).

39 Tris(2,4-pentanedionato)molybdenum(III).

40 Potassium Tetraoxalatouranate(IV).

Chapter VIIA.

41 Sulfur Chloride Pentafluoride.

42 Trifluoromethyl Hypofluorite.

Chapter VIIB.

43 Ammonium Perrhenate.

44 Bis(ethylenediamine)dioxorhenium(V) Chloride, Bis(ethylenediamine)oxohydroxorhenium(V) Perchlorate, and Bis(ethylenediamine)dihydroxorhenium(V) hexachloroplatinate(IV).

Chapter VIII.

45 Diiron Enneacarbonyl.

46 Triiron Dodecacarbonyl.

47 Tricarbonyl(cyclooctatetraene)iron.

48 Iron Carbonyl Complexes of Triphenylphosphine, Triphenylarsine, and Triphenylstibine.

49 Nitrosylpentaamminecobalt(II) Chloride.

50 cis-Dinitrobis(ethylene)cobalt(III) Nitrite and Nitrate.

51 cis-Bromoamminebis(ethylenediamine)cobalt(III) Bromide, cis- and trans-Aquoamminebis(ethylenediamine)cobalt(III) Bromide, and cis-and trans-Aquoamminebis(ethylenediamine)cobalt(III) Nitrate.

52 Sodium Tricarbonatocobaltate(III) 3-Hydrate.

53 Potassium Tetraoxalato-di-μ-hydroxodicobaltate(III) 3-Hydrate (Durrant’s Salt) and Sodium Tetraoxalato-di-μ-hydroxodicobaltate(III) 5-Hydrate.

54 Resolution of the Trioxalatocobaltate(III) Ion.

55 Dichlorotetracarbonyldirhodium.

56 Chlorocarbonylbis(triphenylphosphine)rhodium and Chlorocarbonylbis(triphenylarsine)rhodium.

57 Sodium Hexachlororhodate(III) 2-Hydrate and Potassium Hexachlororhodate(III) 1-Hydrate.

58 Ammonium Hexachloroiridate(IV).

59 Resolution of the Tris(1,10-phenanthroline)nickel(II) Ion.

60 Bis(4-imino-2-pentanonato)nickel(II).

61 Tetraamminepalladium(II) Tetrachloropalladate(II) and trans-Dichlorodiamminepalladium(II).

62 Tris(ethylnenediamine)platinum(IV) Chloride.

63 cis-Dichloro(ethylenediamine)platinum(II).

64 cis- and trans-Tetrachlorobis(diethyl sulfide)platinum(IV).

Noble Gases (Rare Gases, Inert Gases).

65 Introduction to the Chemistry of Compounds of the Noble Gases.

66 Xenon Tetrafluoride.

67 Xenon Hexafluoride.

68 Xenon Difluoride.

Corrections.

Index of Contributors.

Subject Index.

Formula Index.