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Modern Organosilicon Chemistry

Modern Organosilicon Chemistry

Tamejiro Hiyama, Martin Oestreich

ISBN: 978-3-527-81477-0

Aug 2019

244 pages

$184.99

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Description

For the first time in decades, this book summarizes all the important developments in the synthesis and application of organosilicon compounds in catalysis. Edited by two world leaders in the field, it is a must-have reference for all synthetic chemists in academia and industry.
CATALYTIC GENERATION OF NUCLEOPHILIC SILICON
1) Transition-Metal-Catalyzed and -Free Si-B Chemistry

CATALYTIC GENERATION OF ELECTROPHILIC SILICON
2) Si-H Bond Activation by Main-Group Lewis Acids
3) Si-H Bond Activation by Transition-Metal Lewis Acids
4) Cooperative Si-H Bond Activation
5) Silicon-Based Lewis Acids in Catalysis

C-H BOND SILYLATION
6) Transition-Metal-Catalyzed C-H Bond Silylation
7) Transition-Metal-Free C-H Bond Silylation
8) Silyl-Heck Reaction

SILICON-BASED CROSS-COUPLING REACTIONS
9) Hiyama-Type Cross-Couplings
10) Denmark-Type Cross-Couplings

MISCELLANEOUS
11) Lewis-Base Activation of Lewis Acids
12) Hydrosilylation Catalyzed by Earth-Abundant Metals
13) Silylenes (as Ligands) in Catalysis
14) Kinetic Resolution and Desymmetrization by Enantioselective Alcohol Silylation
15) Transfer Hydrosilylation
16) Silicon-Stereogenic Silanes