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Organic Reactions, Volume 73: Allylboration of Carbonyl Compounds

Organic Reactions, Volume 73: Allylboration of Carbonyl Compounds

Dennis G. Hall (Editor), Hugo Lachance (Editor), Scott E. Denmark (Series Editor)

ISBN: 978-0-470-43690-5

Jan 2009

624 pages

In Stock

$193.00

Description

Allylic boron compounds have gained a prominent position as a truly practical class of synthetic reagents in the past twenty-five years. Their main application as a method for the stereoselective synthesis of homoallylic alcohols by allyl-transfer to carbonyl compounds is essentially unmatched. In this process, a new carbon-carbon bond is formed, and up to two new stereogenic centers are created in a predictably controlled manner. Highly effective and general enantioselective variants are available, with countless applications in the total syntheses of polyacetate and polypropionate natural products. Furthermore, the residual allylic unit can be manipulated through a number of different transformations such as oxidative cleavage, olefin metathesis, hydrometalations, and many others. The discovery of Lewis and Brønsted acid catalyzed manifolds recently, has opened new doors for further development of this important reaction. This book provides an up-to-date, comprehensive survey of the literature of this rich chemistry as it pertains to organic synthesis.

Consistent with the goal of Organic Reactions, the content and presentation emphasize the preparative aspects of the reactions, giving considerable attention to the scope and limitations of the individual transformations along with detailed experimental procedures. A tabular survey of all examples of carbonyl allylboration used in organic synthesis is presented in nine tables organized by type of allylic boron reagent with listings within each table according to increasing carbon number of the carbonyl substrates.

The literature is covered through December 2010, including a new listing of nearly 200 literature citations that supplement the original coverage of 834 references used in the earlier hard cover version of the chapter. Allylboration of Carbonyl Compounds is intended to be a useful, easily read reference book for all practitioners of synthetic organic chemistry working in academic and industrial laboratories.

Organic Reactions, Volumes 1 - 74, Set

This item: Organic Reactions, Volume 73: Allylboration of Carbonyl Compounds

Organic Reactions, Volume 67

(Hardcover $205.00)

Organic Reactions, Volume 68

(Hardcover $204.00)

Organic Reactions, Volume 69

(Hardcover $204.00)

Organic Reactions, Volume 71

(Hardcover $204.00)

Organic Reactions, Volume 70

(Hardcover $204.00)

Organic Reactions, Volume 73: Allylboration of Carbonyl Compounds

(Hardcover $193.00)

Organic Reactions, Volume 72

(Hardcover $193.00)

Organic Reactions, Volume 74

(Hardcover $193.00)

Organic Reactions, Volume 1

(Hardcover $261.00)

Organic Reactions, Volume 2

(Hardcover $261.00)

Organic Reactions, Volume 3

(Hardcover $261.00)

Organic Reactions, Volume 4

(Hardcover $261.00)

Organic Reactions, Volume 5

(Hardcover $261.00)

Organic Reactions, Volume 6

(Hardcover $261.00)

Organic Reactions, Volume 7

(Hardcover $261.00)

Organic Reactions, Volume 8

(Hardcover $261.00)

Organic Reactions, Volume 9

(Hardcover $261.00)

Organic Reactions, Volume 10

(Hardcover $261.00)

Organic Reactions, Volume 25

(Hardcover $247.00)

Organic Reactions, Volume 45

(Hardcover $247.00)

Organic Reactions, Volume 26

(Hardcover $247.00)

Organic Reactions, Volume 46

(Hardcover $247.00)

Organic Reactions, Volume 27

(Hardcover $247.00)

Organic Reactions, Volume 58

(Hardcover $247.00)

Organic Reactions, Volume 47

(Hardcover $247.00)

Organic Reactions, Volume 48

(Hardcover $247.00)

Organic Reactions, Volume 49

(Hardcover $247.00)

Organic Reactions, Volume 50

(Hardcover $247.00)

Organic Reactions, Volume 11

(Hardcover $247.00)

Organic Reactions, Volume 12

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Organic Reactions, Volume 13

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Organic Reactions, Volume 14

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Organic Reactions, Volume 15

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Organic Reactions, Volume 16

(Hardcover $232.00)

Organic Reactions, Volume 59

(Hardcover $247.00)

Organic Reactions, Volume 51

(Hardcover $247.00)

Organic Reactions, Volume 52

(Hardcover $247.00)

Organic Reactions, Volume 18

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Organic Reactions, Volume 17

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Organic Reactions, Volume 20

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Organic Reactions, Volume 19

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Organic Reactions, Volume 23

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Organic Reactions, Volume 61

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Organic Reactions, Volume 44

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Organic Reactions, Volume 60

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Organic Reactions, Volume 24

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Organic Reactions, Volume 21

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Organic Reactions, Volume 22

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Organic Reactions, Volume 54

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Organic Reactions, Volume 53

(Hardcover $247.00)

Organic Reactions, Volume 55

(Hardcover $247.00)

Organic Reactions, Volume 56

(Hardcover $247.00)

Organic Reactions, Volume 57

(Hardcover $247.00)

Organic Reactions, Volume 63

(Hardcover $247.00)

Organic Reactions, Volume 62

(Hardcover $247.00)

Organic Reactions, Volume 37

(Hardcover $247.00)

Organic Reactions, Volume 38

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Organic Reactions, Volume 39

(Hardcover $247.00)

Organic Reactions, Volume 40

(Hardcover $247.00)

Organic Reactions, Volume 41

(Hardcover $247.00)

Organic Reactions, Volume 42

(Hardcover $247.00)

Organic Reactions, Volume 43

(Hardcover $247.00)

Organic Reactions, Volume 66

(Hardcover $211.00)

Organic Reactions, Volume 65

(Hardcover $223.95)

Organic Reactions, Volume 64

(Hardcover $247.00)

Organic Reactions, Volume 33

(Hardcover $247.00)

Organic Reactions, Volume 34

(Hardcover $247.00)

Organic Reactions, Volume 35

(Hardcover $247.00)

Organic Reactions, Volume 36

(Hardcover $247.00)

Organic Reactions, Volume 28

(Hardcover $247.00)

Organic Reactions, Volume 29

(Hardcover $247.00)

Organic Reactions, Volume 32

(Hardcover $247.00)

Organic Reactions, Volume 31

(Hardcover $247.00)

Organic Reactions, Volume 30

(Hardcover $247.00)

Original Price:$17,967.95

Purchased Together:$9,320.00

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Organic Reactions, Volumes 1 - 73, Set

This item: Organic Reactions, Volume 73: Allylboration of Carbonyl Compounds

Organic Reactions, Volume 67

(Hardcover $205.00)

Organic Reactions, Volume 68

(Hardcover $204.00)

Organic Reactions, Volume 71

(Hardcover $204.00)

Organic Reactions, Volume 69

(Hardcover $204.00)

Organic Reactions, Volume 70

(Hardcover $204.00)

Organic Reactions, Volume 72

(Hardcover $193.00)

Organic Reactions, Volume 73: Allylboration of Carbonyl Compounds

(Hardcover $193.00)

Organic Reactions, Volume 1

(Hardcover $261.00)

Organic Reactions, Volume 2

(Hardcover $261.00)

Organic Reactions, Volume 3

(Hardcover $261.00)

Organic Reactions, Volume 4

(Hardcover $261.00)

Organic Reactions, Volume 5

(Hardcover $261.00)

Organic Reactions, Volume 6

(Hardcover $261.00)

Organic Reactions, Volume 7

(Hardcover $261.00)

Organic Reactions, Volume 8

(Hardcover $261.00)

Organic Reactions, Volume 9

(Hardcover $261.00)

Organic Reactions, Volume 10

(Hardcover $261.00)

Organic Reactions, Volume 45

(Hardcover $247.00)

Organic Reactions, Volume 58

(Hardcover $247.00)

Organic Reactions, Volume 27

(Hardcover $247.00)

Organic Reactions, Volume 25

(Hardcover $247.00)

Organic Reactions, Volume 46

(Hardcover $247.00)

Organic Reactions, Volume 26

(Hardcover $247.00)

Organic Reactions, Volume 47

(Hardcover $247.00)

Organic Reactions, Volume 50

(Hardcover $247.00)

Organic Reactions, Volume 11

(Hardcover $247.00)

Organic Reactions, Volume 48

(Hardcover $247.00)

Organic Reactions, Volume 49

(Hardcover $247.00)

Organic Reactions, Volume 13

(Hardcover $247.00)

Organic Reactions, Volume 14

(Hardcover $247.00)

Organic Reactions, Volume 15

(Hardcover $247.00)

Organic Reactions, Volume 12

(Hardcover $247.00)

Organic Reactions, Volume 16

(Hardcover $232.00)

Organic Reactions, Volume 59

(Hardcover $247.00)

Organic Reactions, Volume 51

(Hardcover $247.00)

Organic Reactions, Volume 52

(Hardcover $247.00)

Organic Reactions, Volume 17

(Hardcover $247.00)

Organic Reactions, Volume 18

(Hardcover $247.00)

Organic Reactions, Volume 19

(Hardcover $247.00)

Organic Reactions, Volume 20

(Hardcover $247.00)

Organic Reactions, Volume 21

(Hardcover $247.00)

Organic Reactions, Volume 22

(Hardcover $247.00)

Organic Reactions, Volume 23

(Hardcover $247.00)

Organic Reactions, Volume 24

(Hardcover $247.00)

Organic Reactions, Volume 60

(Hardcover $247.00)

Organic Reactions, Volume 61

(Hardcover $247.00)

Organic Reactions, Volume 44

(Hardcover $247.00)

Organic Reactions, Volume 53

(Hardcover $247.00)

Organic Reactions, Volume 54

(Hardcover $247.00)

Organic Reactions, Volume 55

(Hardcover $247.00)

Organic Reactions, Volume 56

(Hardcover $247.00)

Organic Reactions, Volume 57

(Hardcover $247.00)

Organic Reactions, Volume 63

(Hardcover $247.00)

Organic Reactions, Volume 62

(Hardcover $247.00)

Organic Reactions, Volume 37

(Hardcover $247.00)

Organic Reactions, Volume 38

(Hardcover $247.00)

Organic Reactions, Volume 39

(Hardcover $247.00)

Organic Reactions, Volume 40

(Hardcover $247.00)

Organic Reactions, Volume 41

(Hardcover $247.00)

Organic Reactions, Volume 42

(Hardcover $247.00)

Organic Reactions, Volume 43

(Hardcover $247.00)

Organic Reactions, Volume 66

(Hardcover $211.00)

Organic Reactions, Volume 65

(Hardcover $223.95)

Organic Reactions, Volume 64

(Hardcover $247.00)

Organic Reactions, Volume 33

(Hardcover $247.00)

Organic Reactions, Volume 34

(Hardcover $247.00)

Organic Reactions, Volume 35

(Hardcover $247.00)

Organic Reactions, Volume 36

(Hardcover $247.00)

Organic Reactions, Volume 28

(Hardcover $247.00)

Organic Reactions, Volume 29

(Hardcover $247.00)

Organic Reactions, Volume 32

(Hardcover $247.00)

Organic Reactions, Volume 31

(Hardcover $247.00)

Organic Reactions, Volume 30

(Hardcover $247.00)

Original Price:$17,774.95

Purchased Together:$9,145.00

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1. ALLYLBORATION OF CARBONYL COMPOUNDS 1
Hugo Lachance and Dennis G. Hall

CUMULATIVE CHAPTER TITLES BY VOLUME 575

AUTHOR INDEX, VOLUMES 1 - 73 589

CHAPTER AND TOPIC INDEX, VOLUMES 1 - 73 595

?Overall this book is a very useful addition to an organic chemist?s library and is written for both the student and the expert in the field. It will be especially helpful to those who wish to use the allylboration reaction in a synthesis as well as to those interested in furthering the field of allylboration chemistry.? (Journal of the American Chemical Society, October 2009)

?This well written volume of Organic Reactions makes an excellent library resource that comprehensively covers the chemistry of allylboronation of carbonyl compounds. It should make an excellent reference text for graduate students and researchers who are new to this reaction or for researchers who need inspiration for the use of this chemistry.? ( Journal of Medicinal Chemistry , August 2009)