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Rhodium Catalysis for Organic Synthesis: Methods and Reactions

Rhodium Catalysis for Organic Synthesis: Methods and Reactions

Ken Tanaka

ISBN: 978-3-527-34364-5

Mar 2019

640 pages

$255.00

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Description

The use of Rhodium catalysis has increased dramatically during the last decade, so that a range of highly useful reaction types like coupling reactions, cyclizations and many more are performed efficiently. Ken Tanaka presents this field comprehensively in this reference.
RHODIUM(I) CATALYSIS
Rhodium(I)-Catalyzed Asymmetric Hydrogenation
Rhodium(I)-Catalyzed Hydroboration and Related Reactions
Rhodium(I)-Catalyzed Hydroformylation and Related Reactions
Rhodium(I)-Catalyzed Hydroacylation and Related Reactions
Rhodium(I)-Catalyzed (Asymmetric) Addition of Organometallic Reagents to Unsaturated Compounds
Rhodium(I)-Catalyzed Allylation with Alkynes and Allenes
Rhodium(I)-Catalyzed Reductive (Hydrogenative) Carbon-Carbon Bond Formation
Rhodium(I)-Catalyzed ([2+2+1], [4+1], etc) Cycloaddition to Form Five-Membered Rings
Rhodium(I)-Catalyzed ([2+2+2], [4+2], etc) Cycloaddition to Form Six-Membered Rings
Rhodium(I)-Catalyzed Higher-Order ([3+2+2], [5+2], [4+2+2], [5+2+1], [6+2], etc) Cycloaddition
Rhodium(I)-Catalyzed Reactions via Carbon-Hydrogen Bond Cleavage
Rhodium(I)-Catalyzed Reactions via Carbon?Carbon Bond Cleavage

RHODIUM(II) CATALYSIS
Rhodium(II)-Catalyzed (Asymmetric) Carbon-Hydrogen Bond Insertion
Rhodium(II)-Catalyzed Heteroatom-Hydrogen Bond Insertion
Rhodium(II)-Catalyzed Cyclopropanation
Rhodium(II)-Catalyzed Reactions of 1,2,3-Triazoles via Formation of Imino Carbene Complexes
Rhodium(II)-Catalyzed 1,3- and 1,5-Dipolar Cycloaddition

RHODIUM(III) CATALYSIS (5 Chapters, 80 pages)
Rhodium(III)-Catalyzed Carbocyclization via Carbon-Hydrogen Bond Activation
Rhodium(III)-Catalyzed Heterocyclization via Carbon-Hydrogen Bond Activation
Rhodium(III)-Catalyzed Alkenylation, Allylation, and Related Reactions via Carbon-Hydrogen Bond Activation
Modified Cp Ligands for Rhodium(III)-Catalyzed Carbon-Hydrogen Bond Functionalization
Chiral Cp Ligands for Rhodium(III)-Catalyzed Asymmetric Carbon-Hydrogen Bond Functionalization